Optimization of Operating Parameters Using Response Surface Methodology for Preparation of Sugarcane Bagasse-Derived Activated Carbon Via Chemical Activation

Authors

  • Waranya Vitooniput Student, Master of Engineering Program in Energy Engineering, Faculty of Engineering, Khon Kaen University
  • Varinrumpai Seithtanabutara Assistant Professor, Department of Chemical Engineering, Faculty of Engineering, Khon Kaen University

Keywords:

Activated carbon, Zinc Chloride, Box-behnken

Abstract

The sugarcane bagasse-derived activated carbon was synthesized via impregnation-carbonization method. The different weight ratio of ZnCl2 (1:1 to 1:3), carbonization temperature and time of 400-600°C and 60 to 120 min respectively were designed using Box-Behnken Design Minitab. The porous, textural, structural and thermal stability of produced activated carbon will be characterized by N2 adsorption/desorption, SEM, FTIR respectively. SCB-AC of 1298 m2/g  was produced at optimum condition; ZnCl2 concentration, carbonization temperature and time of 2.19 M, 488.89°C and 95.18 min respectively. The produced AC had an irregular structure consisting of both micropores and mesopores, different functional groups and high thermal stability. The SCB-AC with the highest specific surface area of 1355.7 m2/g  can be further applied for the next relevant works.

References

Danish M, Ahmad T. A review on utilization of wood biomass as a sustainable precursor for activated carbon production and application. Renew Sustain Energy Rev. 2018; 87: 1–21.

Elmouwahidi A, Bailón-García E, Pérez-Cadenas AF, Maldonado-Hódar FJ, Carrasco-Marín F. Activated carbons from KOH and H3PO4-activation of olive residues and its application as supercapacitor electrodes. Electrochim Acta. 2017; 229: 219–228.

Viswanathan B, Neel P, Varadarajan T. Methods of activation and specific applications of carbon materials. Methods Act Specif Appl Carbon Mater. 2009; 160.

Pagketanang T, Artnaseaw A, Wongwicha P, Thabuot M. Microporous activated carbon from KOH-activation of rubber Seed-shells for application in capacitor electrode. Vol. 79, Energy Procedia. Elsevier B.V.; 2015: 651-656.

González-García P. Activated carbon from lignocellulosics precursors: A review of the synthesis methods, characterization techniques and applications. Renew Sustain Energy Rev. 2018; 82: 1393–1414.

Bachrun S, Ayurizka N, Annisa S, Arif H. Preparation and characterization of activated carbon from sugarcane bagasse by physical activation with CO2 gas. IOP Conf Ser Mater Sci Eng. 2016; 105(1).

Liou TH. Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chloride activation. Chem Eng J. 2010; 158(2): 129–142.

Sulaiman NS, Hashim R, Mohamad Amini MH, Danish M, Sulaiman O. Optimization of activated carbon preparation from cassava stem using response surface methodology on surface area and yield. J Clean Prod. 2018; 198: 1422–1430.

Nurul-Shuhada Md-Desa, Zaidi Ab Ghani, Suhaimi Abdul-Talib, Chia-Chay Tay. Optimization of activated carbon preparation from spent mushroom farming waste(SMFW) via box-behnken design ( Penyediaan Secara Optimum Arang Teraktif daripada Sisa Tanaman Cendawan Terpakai. Malaysian J Anal Sci. 2016; 20(3): 461–468.

Das S, Mishra S. Box-Behnken statistical design to optimize preparation of activated carbon from Limonia acidissima shell with desirability approach. J Environ Chem Eng. 2017; 5(1): 588–600.

Saka C, BET, TG-DTG, FT-IR, SEM. iodine number analysis and preparation of activated carbon from acorn shell by chemical activation with ZnCl2. J Anal Appl Pyrolysis. 2012; 95: 21–24.

Hu Z, Srinivasan MP, Ni Y. Preparation of mesoporous high-surface-area activated carbon. Adv Mater. 2000; 12(1): 62–65.

Zhu Z, Li A, Yan L, Liu F, Zhang Q. Preparation and characterization of highly mesoporous spherical activated carbons from divinylbenzene-derived polymer by ZnCl2 activation. J Colloid Interface Sci. 2007; 316(2): 628–634.

Demiral H, Demiral, Karabacakoglu B, Tümsek F. Adsorption of textile dye onto activated carbon prepared from industrial waste by ZnCl2 activation. J Int Environ Appl Sci. 2008; 3(5): 381–389.

Tsai WT, Chang CY, Lin MC, Chien SF, Sun HF, Hsieh MF. Adsorption of acid dye onto activated carbons prepared from agricultural waste bagasse by ZnCl2 activation. Chemosphere. 2001; 45(1): 51–58.

Tran VT, Quynh BTP, Phung TK, Ha GN, Nguyen T, Bach LG, et al. Production of activated carbon from sugarcane bagasse by chemical activation with ZnCl2: Preparation and characterization study. Res J Chem Sci. 2016; 6(5): 42–47.

Tsai WT, Chang CY, Lee SL, Wang SY. Thermogravimetric analysis of corn cob impregnated with zinc chloride for preparation of activated carbon. J Therm Anal Calorim. 2001; 63(2): 351–357.

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Published

2021-02-21

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บทความวิจัย