Leaching Behavior of Soluble Substances in Lateritic Soil-Based Geopolymer Incorporating High-Calcium Fly Ash
Keywords:
Geopolymer, Leaching, Lateritic soilAbstract
Geopolymer is a construction material that has gained attention due to its environmental friendliness and the ability to utilize waste materials in its production. However, a significant issue is the leaching of alkaline solutions, such as sodium hydroxide, which may impact ecosystems and human health. This research aims to study the compressive strength and leaching behavior of geopolymer made from lateritic soil mixed with high-calcium fly ash, focusing on varying the concentration of sodium hydroxide and the ratio of sodium silicate to sodium hydroxide. The results showed that a sodium hydroxide concentration of 12 Molar yielded the highest compressive strength, with values of 96.46, 107.18, 110.52, and 117.27 kg/cm² at 3, 7, 14, and 28 days of testing, respectively. Additionally, increasing the sodium silicate to sodium hydroxide ratio improved compressive strength, with a maximum at a 1.50 ratio. However, ratios above 3.00 resulted in rapid setting, leading to a decrease in compressive strength. The leaching study revealed that the pH of the water in which the geopolymer samples were soaked decreased from a maximum of 6.0 to 4.3 at a 12 Molar sodium hydroxide concentration, and the total dissolved solids decreased from 4.337 to 0.965 ppt at 28 days of testing. These findings highlight the importance of controlling the ratio of the solutions in geopolymer production to enhance performance and ensure safety in its application.
References
Xu H, Van Deventer JSJ. The geopolymerization of alumino-silicate minerals. International Journal of Mineral Processing. 2000;59:247–66.
Provis JL, Van Deventer JSJ. Geopolymerization kinetics. 2. Reaction kinetic modelling. Chemical Engineering Science. 2007;62:2318–2329.
Pollution Control Department, Ministry of Science. Community wastewater and wastewater treatment systems. Bangkok: Kurusapa Printing House, Ladprao; 2002.
World Health Organization. Guidelines for drinking-water quality. 4th ed. Incorporating the 1st addendum. Geneva: WHO; 2017.
Duxson P, Provis JL, Lukey GC, Van Deventer JSJ. The role of inorganic polymer technology in the development of ‘green concrete’. Cement and Concrete Research. 2007;37:1590–7.
Bakharev T. Durability of geopolymer materials in sodium and magnesium sulfate solutions. Cement and Concrete Research. 2005;35:1233–46.
Palomo A, Grutzeck MW, Blanco-Varela M. Alkali-activated fly ashes – a cement for the future. Cement and Concrete Research. 1999;29:1323–9.
Fernández-Jiménez A, Palomo A. Composition and microstructure of alkali activated fly ash binder: Effect of the activator. Cement and Concrete Research. 2005;35:1984–92.
Cyriaque Kaze R, Naghizadeh A, Tchadjie L, Adesina A, Noel Yankwa Djobo J, Deutou Nemaleu JG, et al. Lateritic soils based geopolymer materials: A review. Construction and Building Materials. 2022;344:128157.
ASTM International. ASTM D854-23. Standard test methods for specific gravity of soil solids by the water displacement method. West Conshohocken (PA): ASTM International.
ASTM International. ASTM D422-63(2007). Standard test method for particle-size analysis of soils. West Conshohocken (PA): ASTM International.
ASTM International. ASTM D4318-17e1. Standard test methods for liquid limit, plastic limit, and plasticity index of soils. West Conshohocken (PA): ASTM International.
ASTM International. ASTM D2487-17. Standard practice for classification of soils for engineering purposes (Unified Soil Classification System). West Conshohocken (PA): ASTM International.
ASTM International. ASTM D3282-15. Standard practice for classification of soils and soil-aggregate mixtures for highway construction purposes. West Conshohocken (PA): ASTM International.
ASTM International. ASTM C618-22. Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. West Conshohocken (PA): ASTM International.
Gao X, Yu QL, Brouwers HJH. Reaction kinetics, gel character and strength of ambient temperature cured alkali activated slag–fly ash blends. Construction and Building Materials. 2015;80:105–15.
Assi LN, Deaver EE, Ziehl P. Effect of source and particle size distribution on the mechanical and microstructural properties of fly ash-based geopolymer concrete. Construction and Building Materials. 2018;167:372–80.
Sharma PK, Singh JP, Kumar A. Effect of particle size on physical and mechanical properties of fly ash-based geopolymers. Transactions of the Indian Institute of Metals. 2019;72:1323–37.
ASTM International. ASTM C109/C109M-20. Standard test method for compressive strength of hydraulic cement mortars (using 2-in. or [50-mm] cube specimens). West Conshohocken (PA): ASTM International.
Suppiah RR, Nermoggan P, Shafiq N. Experimental investigation of the effects of temperature on the morphological characteristics of geopolymer binders. Journal of Petroleum Exploration and Production Technology. 2022;12:3303–11.
Li Q, Chen S, Zhang Y, Hu Y, Wang Q, Zhou Q, et al. Effect of curing temperature on high-strength metakaolin-based geopolymer composite (HMGC) with quartz powder and steel fibers. Materials. 2022;15:1–18.
Lopes A, Lopes S, Pinto I. Influence of curing temperature on the strength of a metakaolin-based geopolymer. Materials. 2023;16:1–12.
Rihan MAM, Abdalla Abdalla T. Factors influencing compressive strength in fly ash-based geopolymer concrete: a comprehensive review. Iranian Journal of Science and Technology - Transactions of Civil Engineering. 2024;48:1–22.
Morsy M, Alsayed S, Al-Salloum Y, Almusallam T. Effect of sodium silicate to sodium hydroxide ratios on strength and microstructure of fly ash geopolymer binder. The Arabian Journal for Science and Engineering. 2014;39:4333–9.
Van Jaarsveld JGS, Van Deventer JSJ, Lukey GC. The effect of composition and temperature on the properties of fly ash- and kaolinite-based geopolymers. Chemical Engineering Journal. 2002;89:63–73.
Mo B, Zhu H, Cui X, He Y, Gong S. Effect of curing temperature on geopolymerization of metakaolin-based geopolymers. Applied Clay Science. 2014;99:144–8.
Khale D, Chaudhary R. Mechanism of geopolymerization and factors influencing its development: a review. Journal of Materials Science. 2007;42:729–46.
Phair JW, Van Deventer JSJ. Effect of the silicate activator pH on the microstructural characteristics of waste-based geopolymers. International Journal of Mineral Processing. 2002;66:121–43.
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