การสลายไดอะซินอนโดยปฏิกิริยาเสมือนเฟนตันบนตัวเร่งปฏิกิริยามีเหล็กเป็นพื้นฐาน
คำสำคัญ:
ปฏิกิริยาเสมือนเฟนตัน, ไดอะซินอน, ตัวเร่งปฏิกิริยาที่มีเหล็กเป็นพื้นฐานบทคัดย่อ
งานวิจัยนี้มีจุดมุ่งหมายเพื่อศึกษาความเป็นไปได้ในการใช้ตัวเร่งปฏิกิริยา Cu-Fe bimetallic ต่อการสลายไดอะซินอนด้วยกระบวนการคล้ายเฟนตัน โดยทำการศึกษาปริมาณของ Cu บนตัวเร่งปฏิกิริยา ปริมาณตัวเร่งปฏิกิริยา ความเข้มข้นไฮโดรเจนเปอร์ออกไซด์และปริมาณไฮโดรเจนเปอร์ออกไซด์ต่อเวลาเพื่อหาปัจจัยที่ส่งผลต่อการสลายไดอะซินอน จากผลการทดลองยืนยันว่าการเติม Cu บนตัวเร่งปฏิกิริยาส่งผลต่อประสิทธิภาพการสลายไดอะซินอนได้ดีกว่าตัวเร่งปฏิกิริยา Fe รวมถึงการทำปฏิกิริยาที่ไม่เติมไฮโดรเจนเปอร์ออกไซด์และเติมไฮโดรเจนเปอร์ออกไซด์ในสารละลาย ซึ่งตัวเร่งปฏิกิริยา Cu-Fe bimetallic สามารถเพิ่มการเกิดปฏิกิริยารีดอกซ์ได้ดีเมื่อเทียบกับตัวเร่งปฏิกิริยา Fe จากข้อมูลการทดลองพบว่าตัวเร่งปฏิกิริยา 3%Cu-Fe สามารถกำจัดไดอะซินอนได้ถึง 50% ในเวลา 30 นาที ที่ความเข้มข้นเริ่มต้นไดอะซินอน 100 ppm ปริมาณตัวเร่งปฏิกิริยา 1 g/L ปริมาณไฮโดรเจนเปอร์ออกไซด์ 10 mM pH 5
เอกสารอ้างอิง
1. Ahmad J, Mehdi S, Jae KY, Mohammad NJ, Mehrdad F. Photocatalytic degradation of diazinon with illuminated ZnO–TiO2 composite, Journal of the Taiwan Institute of Chemical Engineers. 2015; 50: 100–107.
2. Hilla S, Karl GL. Degradation and by-product formation of diazinon in water during UV and UV/H2O2 treatment, Journal of Hazardous Materials. 2006; 136: 553–559.
3. Chikang W, Yiheng S. Degradation and detoxification of diazinon by sono-Fenton and sono-Fenton-like processes Separation and purification, Technology. 2015; 140: 6–12.
4. Kristina D, Tjasa D, Polonca T, David S. Microorganisms trigger chemical degradation of diazinon, International Biodeterioration & Biodegradation. 2008; 62: 293–296.
5. Mariusz C, Marcin W, Zofia PS. Biodegradation of the organophosphorus insecticide diazinon by Serratia sp and Pseudomonas sp and their use in bioremediation of contaminated soil, Chemosphere. 2009; 76: 494–501.
6. Seyed RM, Mohsen MG, Mona G. Photocatalytic degradation of diazinon under visible light using TiO2/Fe2O3 nanocomposite synthesized by ultrasonic-assisted impregnation method, Separation and Purification Technology. 2017; 175: 418–427.
7. Pimentel M, Oturan N, Dezotti M, Oturan MA. Phenol degradation by advanced electrochemical oxidation process electro-Fenton using a carbon felt cathode, Applied Catalysis B: Environmental. 2008; 83: 140–149.
8. Constapel M, Schellenträger M, Marzinkowski JM, Gab S. Degradation of reactive dyes in wastewater from the textile industry by ozone: Analysis of the products by accurate masses, Water Research. 2009; 43(3): 733-43.
9. Idelaouad R, Valiente M, Yaacoubi A, Tanouti B, Lopez Mesas MR. Decolourization and mineralization of the azo dye C.I. Acid Red 14 by heterogeneous Fenton reaction, Journal of Hazardous Materials. 2011; 186 (1): 745-50.
10. Devi LG, Raju KSA, Kumar SG, Rajashekhar KE. Photodegradation of di azo dye Bismarck Brown by advanced Photo-Fenton process: Influence of inorganic anions and evaluation of recycling efficiency of iron powder. Journal of the Taiwan Institute of Chemical Engineers. 2011; 42(2): 341-9.
11. Khataee A, Salahpour F, Fathinia M, Seyyedi B, Vahid B. Iron rich laterite soil with mesoporous structure for heterogeneous Fenton-like degradation of an azo dye under visible light, Journal of Industrial and Engineering Chemistry. 2015; 26: 129-35.
12. Suchaiya T, Krongthong P, Yoswathana N, Jonglertjunya W. Degradation of Humic acid from aqueous solution by Fenton reaction and microbiological technique. KKU Engineering Journal. 2010; 37(3): 247-255. Thai
13. Chikang W, Yiheng S. Degradation and detoxification of diazinon by sono-Fenton and sono-Fenton-like processes Separation and Purification, Technology. 2015; 140: 6–12.
14. Elena EM, Christophoro C, Konstantinos F. Fenton and Fenton-like oxidation of pesticide acetamiprid in water samples: Kinetic study of the degradation and optimization using response surface methodology, Chemosphere. 2013; 93(9): 1818-1825.
15. Roli S, Chelluboyana Vaishnava R, Poornima P, Pradeep K. Optimization of Fenton oxidation for the removal of methyl parathion in aqueous solution, Perspectives in Science. 2016; 8: 670—672.
16. Shima T, Afshin M, Behzad S, Esmail G,Gordon M. Sonophotocatalytic degradation of diazinon in aqueous solution using iron doped TiO2 nanoparticles, Separation and Purification Technology. 2017; 189: 186–192.
17. Natwat S, Kritin P, Wiparat N, Sutasinee N, Arthit N. Optimization of Decolorization (Somnauk’s Red Dye No. 9) Using Fenton-Like Reaction Over Iron Powder by Box-Behnken Design (BBD), KKU Res J. 2018; 4. Thai
18. Yue Y, Huiqiang LBo L, Ping Y, Min G, Yuexi Z, Guozhen S. Removal of high concentration CI Acid Orange 7 from aqueous solution by zero-valent iron/copper (Fe/Cu) bimetallic particles, Ind. Eng Chem Res. 2014; 53: 2605–2613.
19. Divya T, Renuka NK. Modulated heterogeneous Fenton-like activity of ‘M’ doped nanoceria systems (M= Cu, Fe, Zr, Dy, La): Influence of reduction potential of doped cations, Journal of Molecular Catalysis A: Chemical. 2015; 408: 41–47.
20. Lili Z, Lai L, Yulun N, Chun H. Cu-doped Bi2O3/Bi0 composite as an efficient Fenton-like catalyst for degradation of 2-chlorophenol, Separation and Purification Technology. 2016; 157: 203-208.
21. Pendashteh A, Asghari HF, Chaibakhsh N, Yazdi M, Pendashteh M. Optimized treatment of wastewater containing natural rubber latex by coagulation-flocculation process combined with Fenton oxidation, JMES, 2017; 4015-4023.
22. Mohamed K. Chemical oxidation with hydrogen peroxide for domestic wastewater treatment, Chemical Engineering Journal. 2006; 119: 161–165.
23. Ortega Gomez E, Esteban Garcıa B, Ballesteros Martın M, Fernandez Ibanez P, Sanchez Perez J. Inactivation of natural enteric bacteria in real municipal wastewater by solar photo-Fenton at neutral pH, water research. 2014; 63: 316 -324.
24. Qingqing J, Jun L, Zhaokun X, Bo L. Enhanced reactivity of microscale Fe/Cu bimetallic particles (mFe/Cu) with persulfate (PS) for p-nitrophenol (PNP) removal in aqueous solution, Chemosphere. 2017; 172: 10-20.
25. Bo L, Yunhong Z, Zhaoyun C, Ping Y, Yuexi Z, Juling W. Removal of p-nitrophenol (PNP) in aqueous solution by the micron-scale iron–copper (Fe/Cu) bimetallic particles, Applied Catalysis B: Environmental. 2014; 144: 816 – 830.
26. Junge X, Yunqin L, Baoling Y, Chunhua S, Minglai F, Haojie C, Wenjie S. Large scale preparation of Cu-doped a-FeOOH nanoflowers and their photo-Fenton-like catalytic degradation of diclofenac sodium, Chemical Engineering Journal. 2016; 291: 174–183.
27. Bransfield SJ, Cwiertny DM, Rorerts AL, Fairbrother DH. Influence of copper loading and surface coverage on the reactivity of granular iron toward 1,1,1-trichloroethane. Environ. Sci. Technol. 2006; 40(5): 1485 - 1490.
28. Alireza K, Fatemeh S, Mehrangiz F, Behnam S, Behrouz V. Iron rich laterite soil with mesoporous structure for heterogeneous Fenton-like degradation of an azo dye under visible light, Journal of Industrial and Engineering Chemistry. 2015; 26: 129-135.
29. Keyan L,Yongqin Z, Michael J, Chunshan S, Xinwen G. Facile preparation of magnetic mesoporous Fe3O4/C/Cu composites as high performance Fenton-like catalyst, Applied Surface Science. 2017; 396: 1383-1392.
30. AhmadJonidi J, MehdiShirzad S, Jae K, Mohammad Naimi J, Mehrdad F. Photocatalytic degradation of diazinon with illuminated ZnO–TiO2 composite, Journal of the Taiwan Institute of Chemical Engineers. 2015; 50: 100–107.
31. Seyed Rashid M, Mohsen Mehdipour G, Mona G. Photocatalytic degradation of diazinon under visible light using TiO2/Fe2O3 nanocomposite synthesized by ultrasonic-assisted impregnation method , Separation and Purification Technology. 2017; 175: 418–427.
32. Liang S, Haiou S, Qiang L, Aimin L. Fe/Cu bimetallic catalysis for reductive degradation of nitrobenzene under oxic conditions, Chemical Engineering Journal. 2016; 283: 366–374.
33. Meihua Z, Min C, Guangming Z, Chaosheng Z. Degradation of di (2-ethylhexyl) phthalate in sediment by a surfactant-enhanced Fenton-like process, Chemosphere. 2018; 198: 327-333.
34. Wu J, Lan C, Chan GYS. Organophosphorus pesticide ozonation and formation of oxon intermediates, Chemosphere. 2009; 76: 1308–1314.
35. Wei L, Yucan L, Jinming D, John van L, Christopher P. UV and UV/H2O2 treatment of diazinon and its influence on disinfection by product formation following chlorination, Chemical Engineering Journal. 2015; 274: 39–49.
2. Hilla S, Karl GL. Degradation and by-product formation of diazinon in water during UV and UV/H2O2 treatment, Journal of Hazardous Materials. 2006; 136: 553–559.
3. Chikang W, Yiheng S. Degradation and detoxification of diazinon by sono-Fenton and sono-Fenton-like processes Separation and purification, Technology. 2015; 140: 6–12.
4. Kristina D, Tjasa D, Polonca T, David S. Microorganisms trigger chemical degradation of diazinon, International Biodeterioration & Biodegradation. 2008; 62: 293–296.
5. Mariusz C, Marcin W, Zofia PS. Biodegradation of the organophosphorus insecticide diazinon by Serratia sp and Pseudomonas sp and their use in bioremediation of contaminated soil, Chemosphere. 2009; 76: 494–501.
6. Seyed RM, Mohsen MG, Mona G. Photocatalytic degradation of diazinon under visible light using TiO2/Fe2O3 nanocomposite synthesized by ultrasonic-assisted impregnation method, Separation and Purification Technology. 2017; 175: 418–427.
7. Pimentel M, Oturan N, Dezotti M, Oturan MA. Phenol degradation by advanced electrochemical oxidation process electro-Fenton using a carbon felt cathode, Applied Catalysis B: Environmental. 2008; 83: 140–149.
8. Constapel M, Schellenträger M, Marzinkowski JM, Gab S. Degradation of reactive dyes in wastewater from the textile industry by ozone: Analysis of the products by accurate masses, Water Research. 2009; 43(3): 733-43.
9. Idelaouad R, Valiente M, Yaacoubi A, Tanouti B, Lopez Mesas MR. Decolourization and mineralization of the azo dye C.I. Acid Red 14 by heterogeneous Fenton reaction, Journal of Hazardous Materials. 2011; 186 (1): 745-50.
10. Devi LG, Raju KSA, Kumar SG, Rajashekhar KE. Photodegradation of di azo dye Bismarck Brown by advanced Photo-Fenton process: Influence of inorganic anions and evaluation of recycling efficiency of iron powder. Journal of the Taiwan Institute of Chemical Engineers. 2011; 42(2): 341-9.
11. Khataee A, Salahpour F, Fathinia M, Seyyedi B, Vahid B. Iron rich laterite soil with mesoporous structure for heterogeneous Fenton-like degradation of an azo dye under visible light, Journal of Industrial and Engineering Chemistry. 2015; 26: 129-35.
12. Suchaiya T, Krongthong P, Yoswathana N, Jonglertjunya W. Degradation of Humic acid from aqueous solution by Fenton reaction and microbiological technique. KKU Engineering Journal. 2010; 37(3): 247-255. Thai
13. Chikang W, Yiheng S. Degradation and detoxification of diazinon by sono-Fenton and sono-Fenton-like processes Separation and Purification, Technology. 2015; 140: 6–12.
14. Elena EM, Christophoro C, Konstantinos F. Fenton and Fenton-like oxidation of pesticide acetamiprid in water samples: Kinetic study of the degradation and optimization using response surface methodology, Chemosphere. 2013; 93(9): 1818-1825.
15. Roli S, Chelluboyana Vaishnava R, Poornima P, Pradeep K. Optimization of Fenton oxidation for the removal of methyl parathion in aqueous solution, Perspectives in Science. 2016; 8: 670—672.
16. Shima T, Afshin M, Behzad S, Esmail G,Gordon M. Sonophotocatalytic degradation of diazinon in aqueous solution using iron doped TiO2 nanoparticles, Separation and Purification Technology. 2017; 189: 186–192.
17. Natwat S, Kritin P, Wiparat N, Sutasinee N, Arthit N. Optimization of Decolorization (Somnauk’s Red Dye No. 9) Using Fenton-Like Reaction Over Iron Powder by Box-Behnken Design (BBD), KKU Res J. 2018; 4. Thai
18. Yue Y, Huiqiang LBo L, Ping Y, Min G, Yuexi Z, Guozhen S. Removal of high concentration CI Acid Orange 7 from aqueous solution by zero-valent iron/copper (Fe/Cu) bimetallic particles, Ind. Eng Chem Res. 2014; 53: 2605–2613.
19. Divya T, Renuka NK. Modulated heterogeneous Fenton-like activity of ‘M’ doped nanoceria systems (M= Cu, Fe, Zr, Dy, La): Influence of reduction potential of doped cations, Journal of Molecular Catalysis A: Chemical. 2015; 408: 41–47.
20. Lili Z, Lai L, Yulun N, Chun H. Cu-doped Bi2O3/Bi0 composite as an efficient Fenton-like catalyst for degradation of 2-chlorophenol, Separation and Purification Technology. 2016; 157: 203-208.
21. Pendashteh A, Asghari HF, Chaibakhsh N, Yazdi M, Pendashteh M. Optimized treatment of wastewater containing natural rubber latex by coagulation-flocculation process combined with Fenton oxidation, JMES, 2017; 4015-4023.
22. Mohamed K. Chemical oxidation with hydrogen peroxide for domestic wastewater treatment, Chemical Engineering Journal. 2006; 119: 161–165.
23. Ortega Gomez E, Esteban Garcıa B, Ballesteros Martın M, Fernandez Ibanez P, Sanchez Perez J. Inactivation of natural enteric bacteria in real municipal wastewater by solar photo-Fenton at neutral pH, water research. 2014; 63: 316 -324.
24. Qingqing J, Jun L, Zhaokun X, Bo L. Enhanced reactivity of microscale Fe/Cu bimetallic particles (mFe/Cu) with persulfate (PS) for p-nitrophenol (PNP) removal in aqueous solution, Chemosphere. 2017; 172: 10-20.
25. Bo L, Yunhong Z, Zhaoyun C, Ping Y, Yuexi Z, Juling W. Removal of p-nitrophenol (PNP) in aqueous solution by the micron-scale iron–copper (Fe/Cu) bimetallic particles, Applied Catalysis B: Environmental. 2014; 144: 816 – 830.
26. Junge X, Yunqin L, Baoling Y, Chunhua S, Minglai F, Haojie C, Wenjie S. Large scale preparation of Cu-doped a-FeOOH nanoflowers and their photo-Fenton-like catalytic degradation of diclofenac sodium, Chemical Engineering Journal. 2016; 291: 174–183.
27. Bransfield SJ, Cwiertny DM, Rorerts AL, Fairbrother DH. Influence of copper loading and surface coverage on the reactivity of granular iron toward 1,1,1-trichloroethane. Environ. Sci. Technol. 2006; 40(5): 1485 - 1490.
28. Alireza K, Fatemeh S, Mehrangiz F, Behnam S, Behrouz V. Iron rich laterite soil with mesoporous structure for heterogeneous Fenton-like degradation of an azo dye under visible light, Journal of Industrial and Engineering Chemistry. 2015; 26: 129-135.
29. Keyan L,Yongqin Z, Michael J, Chunshan S, Xinwen G. Facile preparation of magnetic mesoporous Fe3O4/C/Cu composites as high performance Fenton-like catalyst, Applied Surface Science. 2017; 396: 1383-1392.
30. AhmadJonidi J, MehdiShirzad S, Jae K, Mohammad Naimi J, Mehrdad F. Photocatalytic degradation of diazinon with illuminated ZnO–TiO2 composite, Journal of the Taiwan Institute of Chemical Engineers. 2015; 50: 100–107.
31. Seyed Rashid M, Mohsen Mehdipour G, Mona G. Photocatalytic degradation of diazinon under visible light using TiO2/Fe2O3 nanocomposite synthesized by ultrasonic-assisted impregnation method , Separation and Purification Technology. 2017; 175: 418–427.
32. Liang S, Haiou S, Qiang L, Aimin L. Fe/Cu bimetallic catalysis for reductive degradation of nitrobenzene under oxic conditions, Chemical Engineering Journal. 2016; 283: 366–374.
33. Meihua Z, Min C, Guangming Z, Chaosheng Z. Degradation of di (2-ethylhexyl) phthalate in sediment by a surfactant-enhanced Fenton-like process, Chemosphere. 2018; 198: 327-333.
34. Wu J, Lan C, Chan GYS. Organophosphorus pesticide ozonation and formation of oxon intermediates, Chemosphere. 2009; 76: 1308–1314.
35. Wei L, Yucan L, Jinming D, John van L, Christopher P. UV and UV/H2O2 treatment of diazinon and its influence on disinfection by product formation following chlorination, Chemical Engineering Journal. 2015; 274: 39–49.
