Influence of Side Chain on the Inhibition of Aluminium Corrosion in HCl by α-Amino Acids
Article Sidebar
Published:
Aug 22, 2019
Keywords:
Aluminium Corrosion Adsorption DFT Amino acid
Main Article Content
Abstract
Aside from functional groups, aromatic rings have mostly been regarded as zones via which certain inhibitors can protect etching metal parts. Substituent groups generally can be aromatic or non-aromatic, comparison of which is scanty in literature. Among these, amino acids exhibit side substituent chain in addition to amino- and carboxylic carbonyl- functional groups, hence may show unique behaviours in corrosive environment. The side chains of amino acids can vary from to H- to alkyl and then to aromatic. This study is devoted to the investigation of the influence of non-polar, hydrophobic side chain of amino acid homologues (glycine, alanine and phenylalanine) on the inhibition of aluminium corrosion in 0.3 M HCl. Corrosion properties and inhibition mechanism were analysed using mass loss, solid-state characterisation and quantum chemical methods. Potentiodynamic polarisation results confirmed cathodic inhibition, which was relatively less efficient with glycine and phenylalanine. The adsorption of these inhibitors was consistent with Langmuir isotherm and physical mechanism. Activation parameters, topography, electropotential shifts quantum studies and mass loss confirmed the superiority of the inhibiting effect of alanine. It is therefore argued herein that the aromatic carbocyclic moiety of phenylalanine does not dictate its anti-corrosion effect in acidic media, but preferentially, properties such as the adsorption type, corrosion medium, interfacial behaviour of adsorbates and temperature.
Article Details
How to Cite
Shehu, N. U., Gaya, U. I., & Muhammad, A. A. (2019). Influence of Side Chain on the Inhibition of Aluminium Corrosion in HCl by α-Amino Acids. Applied Science and Engineering Progress, 12(3), 186–197. Retrieved from https://ph02.tci-thaijo.org/index.php/ijast/article/view/210894
Issue
Section
Research Articles
References
[1] D. E. J. Talbot and J. D. R. Talbot, Corrosion Science and Technology, 3rd ed. New York: Taylor and Francis, 2018, pp. 159–194.
[2] M. Goyal, S. Kumar, I. Bahadur, C. Verma, and E. E. Ebenso, “Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: A review,” Journal of Molecular Liquids, vol. 256, pp. 565–573, Apr. 2018.
[3] S. Deng, X. Li, and H. Fu, “Acid violet 6B as a novel corrosion inhibitor for cold rolled steel in hydrochloric acid solution,” Corrosion Science, vol. 54, no. 2, pp. 760–768, 2011.
[4] K. Tebbji, N. Faska, A. Tounsi, and H. Oudda, “The effect of some lactones as inhibitors for the corrosion of mild steel in 1M hydrochloric acid,” Materials Chemistry and Physics, vol. 106, no. 2–3, pp. 260–267, 2007.
[5] S. L. Priya, A. Chitra, S. Rajendran, and K. Anuradha, “Corrosion behaviour of aluminium in rain water containing garlic extract,” Surface Engineering, vol. 21, no. 3, pp. 229–231, 2005.
[6] C. Vargel, Corrosion of Aluminium. Amsterdam: Elsevier Ltd, 2018, pp. 185–207.
[7] R. Zandi-zand, A. Ershad-langroudi, and A. Rahimi, “Organic–inorganic hybrid coatings for corrosion protection of 1050 aluminum alloy,” Journal of Non-Crystalline Solids, vol. 351, no. 14–15, pp. 1307–1311, 2005
[8] R. Rosliza, A. Nora’aini, and W. B. Wan Nik, “Study on the effect of vanillin on the corrosion inhibition of aluminum alloy,” Journal of Applied Electrochemistry, vol. 40, no. 4, pp. 833–840, 2010.
[9] P. Arellanes-Lazoda, O. Olivares-Xometl, D. Guzmán-Lucero, N. V. Likhanova, and M. A. Domínguez-Aguilar, I. V. Lijanova, E. Arce-Estrada, “The inhibition of aluminum corrosion in sulfuric acid by poly(1-vinyl-3-alkyl-imidazolium hexafluorophosphate,” Molecules, vol. 7, no. 8, pp. 5711–5734, 2014.
[10] E. Li, J. Wu, D. Zhang, Y. Sun, and J. Chen, “D-phenylalanine inhibits the corrosion of Q235 carbon steel caused by Desulfovibrio sp.,” International Biodeterioration & Biodegradation, vol. 127, pp. 178–184, 2018.
[11] Q. Zhao, T. Tang, P. Dang, Z. Zhang, and F. Wang, “The corrosion inhibition effect of triazinedithiol inhibitors for aluminium alloy in a 1M HCl solution,” Metals, vol. 7, no. 2, pp. 1–11, 2017.
[12] D. Landolt, Corrosion and Surface Chemistry of Metals. Switzerland: EPFL Press, 2007, pp. 548–550.
[13] I. B. Obot and N. O. Obi-Egbedi, “Anti-corrosive properties of xanthone on mild steel corrosion in sulphuric acid: Experimental and theoretical investigations,” Current Applied Physics, vol. 11, no. 3, pp. 382–392, 2011.
[14] A. S. Patel, V. A. Panchal, G. V. Mudaliar, and N. K. Shah, “Impedance spectroscopic study of corrosion inhibition of Al-Pure by organic Schiff base in hydrochloric acid,” Journal of Saudi Chemical Society, vol. 17, no. 1, pp. 53–59, 2013.
[15] A. K. Satapathy, G. Gunasekaran, S. C. Sahoo, K. Amit, and P. V. Rodriquez, “Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution,” Corrosion Science, vol. 51, no. 12, pp. 2848–2856, 2009.
[16] S. Rajendran, J. Jeyasundari, P. Usha, J. A. Selvi, B. Narayanasamy, A. P. P. Regis, and P. Rengan, “Corrosion behaviour of aluminium in the presence of an aqueous extract of Hibiscus Rosa-sinensis,” Portugaliae Electrochimica Acta, vol. 27, no. 2, pp. 153–164, 2009.
[17] Y. Qiang, S. Zhang, B. Tan, and S. Chen, “Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution,” Corrosion Science, vol. 133, pp. 6–18, 2018.
[18] L. Hamadi, S. Mansouri, K. Oulmi, and A. Kereche, “The use of amino acids as corrosion inhibitors for metals: A review,” Egyptian Journal of Petroleum, vol. 27, no. 4, pp. 1157–1165, 2018.
[19] C. Zhu, H. X. Yang, Y. Z. Wang, D. Q. Zhang, Y. Chen, and L. X. Gao, “Synergistic effect between glutamic acid and rare earth cerium (III) as corrosion inhibitors on AA5052 aluminum alloy in neutral chloride medium,” Ionics, vol. 25, no. 3, pp. 1395–1406, 2018.
[20] J. Bao, H. Zhang, X. Zhao, and J. Deng, “Biomass polymeric microspheres containing aldehyde groups: Immobilizing and controlled-releasing amino acids as green metal corrosion inhibitor,” Chemical Engineering Journal, vol. 341, pp. 146–156, 2018.
[21] Z. Shi, M. Liu, and S. Atrens, “Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation,” Corrosion Science, vol. 52, no. 2, pp. 579–588, 2010.
[22] V. Cicek and B. Al-Numan, Corrosion Chemistry. United States of America: Scrivener Publishing LLC & Wiley & Sons, 2011, pp. 7–14.
[23] E. S. Ferreira, C. Giacomelli, and A. Spinelli, “Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel,” Materials Chemistry and Physics, vol. 83, no. 1, pp. 129–134, 2004.
[24] E. A. Noor, “Evaluation of inhibitive action of some quaternary n-heterocyclic compounds on the corrosion of Al–Cu alloy in hydrochloric acid,” Materials Chemistry and Physics, vol. 114, no. 2–3, pp. 533–541, 2009.
[25] T. Engel and P. Reid, Physical Chemistry. San Francisco: Pearson Education, 2006, pp. 925–926.
[26] N. Soltani, N. Tavakkoli, M. Khayatkashani, and M. R. Jalali, “Green approach to corrosion inhibition of 304 stainless steel in hydrochloric acid solution by the extract of Salvia officinalis leaves,” Corrosion Science, vol. 62, no. pp. 122–135, 2012.
[27] J. M. Hornback, Organic Chemistry. Taiwan: Thomson Brooks/Cole, 2006, pp. 1126.
[28] L. Fragoza-Mar, O. Olivares-Xometl, M. A. Domínguez-Aguilar, E. A. Flores, P. Arellanes-Lozada, and F. Jiménez-Cruz, “Corrosion inhibitor activity of 1,3-diketone malonates for mild steel in aqueous hydrochloric acid solution,” Corrosion Science, vol. 61, pp. 171–184, 2012.
[29] M. Dehdab, M. Shahraki, and S. M. Habibi‑Khorassani, “Theoretical study of inhibition efficiencies of some amino acids on corrosion of carbon steel in acidic media: Green corrosion inhibitors,” Amino Acids, vol. 48, no. 1, pp. 291–306, 2015.
[30] K. F. Khaled, “Corrosion control of copper in nitric acid solutions using some amino acids–A combined experimental and theoretical study,” Corrosion Science, vol. 52, no. 10, pp. 3225–3234, 2010.
[31] S. Kaya, C. Kaya, L. Guo, F. Kandemirli, B. Tüzün, I. Uğurlu, L. H. Madkour, and M. Saraçoğlu, “Quantum chemical and molecular dynamics simulation studies on inhibition performances of some thiazole and thiadiazole derivatives against corrosion of iron,” Journal of Molecular Liquids, vol. 219, pp. 497–504, 2016.
[32] L. Guo, S. Kaya, I. B. Obot, X. Zheng, and Y. Qiang, “Toward understanding the anticorrosive mechanism of some thiourea derivatives for carbon steel corrosion: A combined DFT and molecular dynamics investigation,” Journal of Colloid and Interface Science, vol. 506, pp. 478–485, 2017.
[33] E. Alibakhshi, M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, M. Mahdavian, and M. Motamedi, “Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: Experimental, molecular dynamics, Monte Carlo and quantum mechanics study,” Journal of Molecular Liquids, vol. 255, pp. 185–198, 2018.
[34] S. K. Saha, P. Gosh, A. Hens, and N. C. Murmu, “Density functional theory and molecular dynamics simulation study on corrosion inhibition performance of mild steel by mercapto-quinoline Schiff base corrosion inhibitor,” Physica E: Lowdimensional Systems and Nanostructures, vol. 66, pp. 332–341, 2015.
[2] M. Goyal, S. Kumar, I. Bahadur, C. Verma, and E. E. Ebenso, “Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: A review,” Journal of Molecular Liquids, vol. 256, pp. 565–573, Apr. 2018.
[3] S. Deng, X. Li, and H. Fu, “Acid violet 6B as a novel corrosion inhibitor for cold rolled steel in hydrochloric acid solution,” Corrosion Science, vol. 54, no. 2, pp. 760–768, 2011.
[4] K. Tebbji, N. Faska, A. Tounsi, and H. Oudda, “The effect of some lactones as inhibitors for the corrosion of mild steel in 1M hydrochloric acid,” Materials Chemistry and Physics, vol. 106, no. 2–3, pp. 260–267, 2007.
[5] S. L. Priya, A. Chitra, S. Rajendran, and K. Anuradha, “Corrosion behaviour of aluminium in rain water containing garlic extract,” Surface Engineering, vol. 21, no. 3, pp. 229–231, 2005.
[6] C. Vargel, Corrosion of Aluminium. Amsterdam: Elsevier Ltd, 2018, pp. 185–207.
[7] R. Zandi-zand, A. Ershad-langroudi, and A. Rahimi, “Organic–inorganic hybrid coatings for corrosion protection of 1050 aluminum alloy,” Journal of Non-Crystalline Solids, vol. 351, no. 14–15, pp. 1307–1311, 2005
[8] R. Rosliza, A. Nora’aini, and W. B. Wan Nik, “Study on the effect of vanillin on the corrosion inhibition of aluminum alloy,” Journal of Applied Electrochemistry, vol. 40, no. 4, pp. 833–840, 2010.
[9] P. Arellanes-Lazoda, O. Olivares-Xometl, D. Guzmán-Lucero, N. V. Likhanova, and M. A. Domínguez-Aguilar, I. V. Lijanova, E. Arce-Estrada, “The inhibition of aluminum corrosion in sulfuric acid by poly(1-vinyl-3-alkyl-imidazolium hexafluorophosphate,” Molecules, vol. 7, no. 8, pp. 5711–5734, 2014.
[10] E. Li, J. Wu, D. Zhang, Y. Sun, and J. Chen, “D-phenylalanine inhibits the corrosion of Q235 carbon steel caused by Desulfovibrio sp.,” International Biodeterioration & Biodegradation, vol. 127, pp. 178–184, 2018.
[11] Q. Zhao, T. Tang, P. Dang, Z. Zhang, and F. Wang, “The corrosion inhibition effect of triazinedithiol inhibitors for aluminium alloy in a 1M HCl solution,” Metals, vol. 7, no. 2, pp. 1–11, 2017.
[12] D. Landolt, Corrosion and Surface Chemistry of Metals. Switzerland: EPFL Press, 2007, pp. 548–550.
[13] I. B. Obot and N. O. Obi-Egbedi, “Anti-corrosive properties of xanthone on mild steel corrosion in sulphuric acid: Experimental and theoretical investigations,” Current Applied Physics, vol. 11, no. 3, pp. 382–392, 2011.
[14] A. S. Patel, V. A. Panchal, G. V. Mudaliar, and N. K. Shah, “Impedance spectroscopic study of corrosion inhibition of Al-Pure by organic Schiff base in hydrochloric acid,” Journal of Saudi Chemical Society, vol. 17, no. 1, pp. 53–59, 2013.
[15] A. K. Satapathy, G. Gunasekaran, S. C. Sahoo, K. Amit, and P. V. Rodriquez, “Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution,” Corrosion Science, vol. 51, no. 12, pp. 2848–2856, 2009.
[16] S. Rajendran, J. Jeyasundari, P. Usha, J. A. Selvi, B. Narayanasamy, A. P. P. Regis, and P. Rengan, “Corrosion behaviour of aluminium in the presence of an aqueous extract of Hibiscus Rosa-sinensis,” Portugaliae Electrochimica Acta, vol. 27, no. 2, pp. 153–164, 2009.
[17] Y. Qiang, S. Zhang, B. Tan, and S. Chen, “Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution,” Corrosion Science, vol. 133, pp. 6–18, 2018.
[18] L. Hamadi, S. Mansouri, K. Oulmi, and A. Kereche, “The use of amino acids as corrosion inhibitors for metals: A review,” Egyptian Journal of Petroleum, vol. 27, no. 4, pp. 1157–1165, 2018.
[19] C. Zhu, H. X. Yang, Y. Z. Wang, D. Q. Zhang, Y. Chen, and L. X. Gao, “Synergistic effect between glutamic acid and rare earth cerium (III) as corrosion inhibitors on AA5052 aluminum alloy in neutral chloride medium,” Ionics, vol. 25, no. 3, pp. 1395–1406, 2018.
[20] J. Bao, H. Zhang, X. Zhao, and J. Deng, “Biomass polymeric microspheres containing aldehyde groups: Immobilizing and controlled-releasing amino acids as green metal corrosion inhibitor,” Chemical Engineering Journal, vol. 341, pp. 146–156, 2018.
[21] Z. Shi, M. Liu, and S. Atrens, “Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation,” Corrosion Science, vol. 52, no. 2, pp. 579–588, 2010.
[22] V. Cicek and B. Al-Numan, Corrosion Chemistry. United States of America: Scrivener Publishing LLC & Wiley & Sons, 2011, pp. 7–14.
[23] E. S. Ferreira, C. Giacomelli, and A. Spinelli, “Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel,” Materials Chemistry and Physics, vol. 83, no. 1, pp. 129–134, 2004.
[24] E. A. Noor, “Evaluation of inhibitive action of some quaternary n-heterocyclic compounds on the corrosion of Al–Cu alloy in hydrochloric acid,” Materials Chemistry and Physics, vol. 114, no. 2–3, pp. 533–541, 2009.
[25] T. Engel and P. Reid, Physical Chemistry. San Francisco: Pearson Education, 2006, pp. 925–926.
[26] N. Soltani, N. Tavakkoli, M. Khayatkashani, and M. R. Jalali, “Green approach to corrosion inhibition of 304 stainless steel in hydrochloric acid solution by the extract of Salvia officinalis leaves,” Corrosion Science, vol. 62, no. pp. 122–135, 2012.
[27] J. M. Hornback, Organic Chemistry. Taiwan: Thomson Brooks/Cole, 2006, pp. 1126.
[28] L. Fragoza-Mar, O. Olivares-Xometl, M. A. Domínguez-Aguilar, E. A. Flores, P. Arellanes-Lozada, and F. Jiménez-Cruz, “Corrosion inhibitor activity of 1,3-diketone malonates for mild steel in aqueous hydrochloric acid solution,” Corrosion Science, vol. 61, pp. 171–184, 2012.
[29] M. Dehdab, M. Shahraki, and S. M. Habibi‑Khorassani, “Theoretical study of inhibition efficiencies of some amino acids on corrosion of carbon steel in acidic media: Green corrosion inhibitors,” Amino Acids, vol. 48, no. 1, pp. 291–306, 2015.
[30] K. F. Khaled, “Corrosion control of copper in nitric acid solutions using some amino acids–A combined experimental and theoretical study,” Corrosion Science, vol. 52, no. 10, pp. 3225–3234, 2010.
[31] S. Kaya, C. Kaya, L. Guo, F. Kandemirli, B. Tüzün, I. Uğurlu, L. H. Madkour, and M. Saraçoğlu, “Quantum chemical and molecular dynamics simulation studies on inhibition performances of some thiazole and thiadiazole derivatives against corrosion of iron,” Journal of Molecular Liquids, vol. 219, pp. 497–504, 2016.
[32] L. Guo, S. Kaya, I. B. Obot, X. Zheng, and Y. Qiang, “Toward understanding the anticorrosive mechanism of some thiourea derivatives for carbon steel corrosion: A combined DFT and molecular dynamics investigation,” Journal of Colloid and Interface Science, vol. 506, pp. 478–485, 2017.
[33] E. Alibakhshi, M. Ramezanzadeh, G. Bahlakeh, B. Ramezanzadeh, M. Mahdavian, and M. Motamedi, “Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: Experimental, molecular dynamics, Monte Carlo and quantum mechanics study,” Journal of Molecular Liquids, vol. 255, pp. 185–198, 2018.
[34] S. K. Saha, P. Gosh, A. Hens, and N. C. Murmu, “Density functional theory and molecular dynamics simulation study on corrosion inhibition performance of mild steel by mercapto-quinoline Schiff base corrosion inhibitor,” Physica E: Lowdimensional Systems and Nanostructures, vol. 66, pp. 332–341, 2015.