Adsorption Soluble Cutting Fluid Emulsion by Modified Chitosan with SLES
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Published:
Dec 19, 2019
Keywords:
Adsorption Soluble cutting fluid emulsion Modified chitosan Adsorption isotherm Batch design
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Abstract
This study examined the effect of modifying chitosan (MC) with sodium lauryl ether sulfate (SLES) in adsorbing soluble cutting fluid emulsion (SCFE). The adsorbent was prepared by the addition of SLES to chitosan solution followed by sulfuric acid immersion. Batch adsorption was carried out as a function of initial concentration of the soluble cutting fluid emulsion. The point of zero charge of the adsorbent was also measured at pH 1.9. The percent adsorption was calculated and found out to decrease, whereas the adsorption capacity increases as the initial concentration of the adsorbate increases. Experimental results showed that using 2.0 g of the modified chitosan in a 72,227 mg/L soluble cutting fluid emulsion concentration, a 2,518.8 mg/g adsorption capacity was calculated. Models of Langmuir and Freundlich were applied to describe the adsorption isotherm together with coefficient of determination and chi-square error function calculations. The Langmuir isotherm best fitted the experimental data of the modified chitosan. In addition, the significant uptake of the soluble cutting fluid emulsion was demonstrated by the changes in the FTIR spectra and the heat of combustion of the modified chitosan before and after the adsorption process.
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Puangpun, N., Suwimon, I., Piyamongkala, K., & R. Manguiam, V. L. (2019). Adsorption Soluble Cutting Fluid Emulsion by Modified Chitosan with SLES. Applied Science and Engineering Progress, 12(4), 243–252. Retrieved from https://ph02.tci-thaijo.org/index.php/ijast/article/view/232546
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References
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[2] E. Brinksmeier, D. Meyer, A. G. Huesmann- Cordes, and C. Herrmann, “Metalworking fluids-mechanisms and performance,” CIRP Annals-Manufacturing Technology, vol. 64, no. 2, pp. 605–629, 2015.
[3] M. Osama, A. Singh, R. Walvekar, M. Khalid, T. C. S. M. Gupta, and W. W. Yin, “Recent developments and performance review of metal working fluids,” Tribology International, vol. 114, pp. 389–401, 2017.
[4] J. M. Benito, A. Cambiella, A. Lobo, G. Gutiérrez, J. Coca, and C. Pazos, “Formulation, characterization and treatment of metalworking oil-in-water emulsions,” Clean Technologies and Environmental Policy, vol. 12, no. 1, pp. 31–41, 2010.
[5] M. Schwarz, M. Dado, R. Hnilica, and D. Veverkavá, “Environmental and health aspects of metal working fluid use,” Polish Journal of Environmental Studies, vol. 24, no. 1, pp. 37–45, 2015.
[6] S. Debnath, M. M. Reddy, and Q. R. Yi, “Environmental friendly cutting fluids and cooling techniques in machining: A review,” Journal of Cleaner Production, vol. 83, pp 33–47, 2014.
[7] E. Demirbas and M. Kobya, “Operating cost and treatment of metal working fluid wastewater by chemical coagulation and electrocoagulation process,” Process Safety and Environmental Protection, vol. 105, pp. 79–90, 2017.
[8] M. Kobya, E. Demirbas, M. Bayramoglu, and M. T. Sensoy, “Optimization of electrocoagulation process for the treatment of metal cutting wastewaters with response surface methodology,” Water, Air, & Soil Pollution, vol. 215, no. 1–4, pp. 399–410, 2011.
[9] N. Moulai-Mostefa, M. Frappart, O. Akoum, L. Ding, and M. Y. Jaffrin, “Separation of water from metal working emulsions by ultrafiltration using vibratory membranes,” Journal of Hazardous Materials, vol. 177, no. 1–3, pp. 978–982, 2010.
[10] S. Jagadevana, N. J. Grahamb, and I. P. Thompson, “Treatment of waste metal working fluid by a hydrid ozone-biological process,” Journal of Hazardous Materials, vol. 244–245, pp. 394–402, 2013.
[11] J. Sánchez-Oneto, J. R. Portela, E. Nebot, and E. Martínez de la Ossa, “Hydrothermal oxidation: Application to the treatment of different cutting fluid wastes,” Journal of Hazardous Materials, vol. 144, no. 3, pp. 639–644, 2007.
[12] G. N. Mathavan and T. Viraraghavan, “Use of peat in the treatment of oily waters,” Water, Air & Soil Pollution, vol. 45 no. 1–2, pp. 17–26, 1989.
[13] C. Solisio, A. Lodi, A. Converti, and M. D. Borghi, “Removal of exhausted oils by adsorption on mixed Ca and Mg oxides,” Water Research, vol. 36, no. 4, pp. 899–904, 2002.
[14] A. Cambiella, E. Ortea, G. Rios, J. M. Benito, C. Pozos, and J. Coca, “Treatment of oil-in-water emulsions: Performance of a sawdust bed filter,” Journal of Hazardous Materials, vol. 131, no. 1–3, pp. 195–199, 2006.
[15] K. Piyamongkala, L. Mekasut, and S. Pongstabodee, “Cutting fluid effluent removal by adsorption on chitosan and sds-modified chitosan,” Macromolecular Research, vol. 16, no. 6, pp. 492–502, 2008.
[16] S. Tiwari, V. K. Gupta, P. C. Pandey, H. Singh, and P. K. Mishra, “Adsorption chemistry of oilin- water emulsion from spent oil based cutting fluids using sawdust of Mangifera indica,” Journal of International Environmental Application & Science, vol. 4, no. 1, pp. 99–107, 2009.
[17] A. R. Tembhurka and R. Deshpande, “Powdered activated lamon peels as adsorbent for removal of cutting oil from wastewater,” Journal of Hazardous, Toxic, and Radioactive Waste, vol. 16, no. 4, pp. 311–315, 2012.
[18] S. S. Elanchezhiyan, N. Sivasurian, and S. Meenakshi, “Recovery of oil from oil-in-water emulsion using biopolymers by adsorption method,” International Journal of Biological Macromolecules, vol. 70, pp. 399–407, 2014.
[19] N. Sivasurian, S. S. Elanchezhiyan, and S. Meenakshi, “Adsorption behavior of cutting oil on lanthanum coordinated chitosan flakes from oil-in-water emulsion,” Journal of Chitin and Chitosan Science, vol. 3, no. 1, pp. 11–20, 2015.
[20] S. S. Elanchezhiyan and S. Meenakshi, “Facile synthesis of metal incorporated chitin for the recovery of oil from oil-in-water emulsion using adsorption method,” Journal of Cleaner Production, vol. 139, pp. 1339–1350, 2016.
[21] G. Z. Kyzas and D. N. Bikiaris, “Recent modifications of chitosan for adsorption applications: A critical and synthematic review,” Marine Drugs, vol. 13, no. 1, pp. 312–337, 2015.
[22] T. Anitha, P. S. Kumar, and K. S. Kumar, “Binding of Zn(II) ions to chitosan-PVA blend in aqueous environment: Adsorption kinetics and equilibrium studies,” Environmental Progress & Energy, vol. 34, no. 1, pp. 15–22, 2015.
[23] N. A. Kalkan, S. Aksoy, E. A. Aksoy, and N. Hasirci, “Adsorption of reactive yellow 145 onto chitosan coated magnetic nanoparticles,” Journal of Applied Polymer Science, vol. 124, no. 1, pp. 576–584, 2012.
[24] A. Sowmya and S. Meenakshi, “An efficient and regenerable quaternary amine modified chitosan beads for the removal of nitrate and phosphate anions,” Journal of Environmental Chemical Engineering, vol. 1, no. 4, pp. 906–915, 2013.
[25] F. Amri, S. Husseinsyah, and K. Hussin, “Effect of sodium dodecyl sulfate on mechanical and thermal properties of polypropylene/chitosan composites,” Journal of Thermoplastic Composite Material, vol. 26, no. 7, pp. 878–892, 2011.
[26] K. Piyamongkala, N. Puangpun, and I. Wuwimon, “Thai Petty Patent,” No. 15346, Jul. 18, 2019.
[27] W. S. W. Ngah, L. C. Teong, R. H. Toh, and M. A. K. M. Hanafiah, “Utilization of chitosan-zeolite composite in the removal of Cu(II) from aqueous solution: Adsorption, desorption and fixed bed column studies,” Chemical Engineering Journal, vol. 209, pp. 46–53, 2012.
[28] D. L. Pavia, G. M. Lampman, and G. S. Kriz, Introduction to Spectroscopy, 3rd ed., Orlando, USA: Harcourt, 2001, pp. 13–101.
[29] G. Moussavi and R. Khosravi, “The removal of cationic dyes from aqueous solutions by adsorption onto pistachio hull waste,” Chemical Engineering Research and Design, vol. 89, no. 10, pp. 2182–2189, 2011.
[30] E. Bazrafshan, A. A. Zarei, H. Nadi, and M. A. Zazouli, “Adsorption removal of methyl orange and reactive red 198 dyes by Moringa peregrina ash,” Indian Journal of Chemical Engineering, vol. 21, no. 2, pp. 105–113, 2014.
[31] N. Naowanat, N. Thouchprasitchai, and S. Pongstabodee, “Adsorption of emulsified oil from metalworking fluid on activated bleaching earth-chitosan-SDS composites: Optimization, kinetics, isotherms,” Journal of Environmental Management, vol. 169, pp. 103–115, 2016.
[32] M. A. Abdullah, L. Chiang, and M. Nadeem, “Comparative evaluation of adsorption kinetics and isothermals of natural product removal by Amberlite polymeric adsorbents,” Chemical Engineering Journal, vol. 146, no. 3, pp. 370–376, 2009.
[33] B. Crittenden and W. J. Thomas, Adsorption Technology & Design. Oxford, England: Butterworth- Heinemann, 1998, pp. 134–142.
[34] K. Y. Foo and B. H. Hameed, “Insights into the modeling of adsorption isotherm systems,” Chemical Engineering Journal, vol. 156, no. 1, pp. 2–10, 2010.
[35] Y. S. Ho, W. T. Chiu, and C. C. Wang, “Regression analysis for the sorption isotherms of basic dyes on sugarcane dust,” Bioresource Technology, vol. 96, no. 11, pp. 1285–1291, 2005.
[36] V. Vadivelan and K. V. Kumar, “Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk,” Journal of Colloid and Interface Science, vol. 286, no. 1, pp. 90–100, 2005.
[37] P. S. Kumar, S. Ramalingam, V. Sathyaselvabala, S. D. Kirupha, A. Murugesan, and S. Sivanesan, “Removal of cadmium(II) from aqueous solution by agricultural waste cashew nut shell,” Korean Journal of Chemical Engineering, vol. 29, no. 6, pp. 756–768, 2012.
[38] Y. S. Ho and G. McKay, “Sorption of dye from aqueous solution by peat,” Chemical Engineering Journal, vol. 70, no. 2, pp. 115–124, 1998.
[39] A. P. Sincero and G. A. Sincero, Physical- Chemical Treatment of Water and Wastewater. Boca Raton, USA: IWA Publishing, 2003, pp. 391–405.