Modification of Waste Leather Trimming with in Situ Generated Silver Nanoparticles by One Step Method
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Published:
Mar 19, 2021
Keywords:
Industrial waste Leather trimming In situ method Silver and silver oxide nanoparticles Antibacterial activity
Main Article Content
Abstract
Waste leather trimming (WLT) was modified by in situ generation of silver nanoparticles (AgNPs) and silver oxide nanoparticles (Ag2ONPs) by one step thermal assisted method. The modified WLT was analyzed by FTIR, SEM, EDS, XRD and TGA techniques and antibacterial analysis. The generated silver based nanoparticles had a mean size of 93 nm. The FTIR spectra revealed no major changes between WLT and modified WLT. The XRD studies indicated additional peaks in the diffractogram of modified WLT which belonged to AgNPs and Ag2ONPs. The unmodified WLT had four inflection temperatures at 89, 303, 454, and 785°C while these values for the modified WLT were 84, 211, 305, and 328°C indicating a slight lowering of thermal stability due to the catalytic activity of the generated silver based nanoparticles. Further, the modified WLT formed the inhibition zones against E.coli, P.aeruinosa, S.aeureus and B.lichinomonas bacteria with diameters of 33, 36, 29, and 30 mm respectively. Hence, the modified WLT can be considered as filler for making low cost antibacterial biocomposites.
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Ashok, B., Umamahesh, M., Hariram, N., Siengchin, S., & Rajulu, A. V. (2021). Modification of Waste Leather Trimming with in Situ Generated Silver Nanoparticles by One Step Method. Applied Science and Engineering Progress, 14(2), 236–246. https://doi.org/10.14416/j.asep.2021.01.007
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References
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[2] J. W. Lu, N. B. Chang, and L. Liao, “Environmental informatics for solid and hazardous waste management: Advances, challenges, and perspectives,” Critical Reviews in Environmental Science and Technology, vol. 43, no. 15, pp. 1557– 1656, 2013.
[3] A. Bhatnagar and M. Sillanpaa, “Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment - A review,” Chemical Engineering Journal, vol. 157, no. 2–3, pp. 277–296, 2010.
[4] M. Safiuddin, M. Z. Jumaat, M. A. Salam, M. S. Islam, and R. Hashim, “Utilization of solid wastes in construction materials,” International Journal of Physical Sciences, vol. 5, no. 13, pp. 1952– 1963, 2010.
[5] J. C. Hargreaves, M. S. Adl, and P. R. Warman, “A review of the use of composted municipal solid waste in agriculture,” Agriculture, Ecosystems and Environment, vol. 123, no. 1–3, pp. 1–14, 2008.
[6] S. Joseph, T. S. Ambone, A. V. Salvekar, S. N. Jaisankar, P. Saravanan, I. K. Kapdan, and F. Kargi, “Bio-hydrogen production from waste materials,” Enzyme and Microbial Technology, vol. 38, no. 5, pp. 569–582, 2006.
[7] J. Kanagaraj, K. C. Velappan, N. K. Chandra Babu, and S. Sadulla, “Solid wastes generation in the leather industry and its utilization for cleaner environment - A review,” Journal of Scientific and Industrial Research, vol. 65, pp. 541–548, 2006.
[8] R. K. Henry, Z. Yongsheng, and D. Jun, “Municipal solid waste management challenges in developing countries–Kenyan case study,” Waste Management, vol. 26, no. 1, pp. 92–100, 2006.
[9] S. P. Goutam, A. Kumar, D. Kumar, R. Shastri, and A. K. Yadav, “Application of supercritical carbon dioxide in the leather industry,” Industrial Applications of Green Solvents, vol. 1, no. 50, pp. 147–164, 2019.
[10] O. Yılmaz, I. C. Kantarli, M. Yuksel, M. Saglam, and J. Yanik, “Conversion of leather wastes to useful products,” Resources, Conservation and Recycling, vol. 49, pp. 436–448, 2007.
[11] K. Yorseng, N. Rajini, S. Siengchin, N. Ayrilmis, and A. V. Rajulu, “Mechanical and thermal properties of spent coffee bean filler/poly (3-hydroxybutyrate-co-3-hydroxyvalerate) biocomposites: Effect of recycling,” Process Safety and Environmental Protection, vol. 124, pp. 187–195, 2019.
[12] T. S. M. Kumar, R. Nagarajan, M. Jawaid, A. V. Rajulu, and S. Siengchin, “Utilization of chemically treated municipal solid waste (spent coffee bean powder) as reinforcement in cellulose matrix for packaging applications,” Waste Management, vol. 69, pp. 445–454, 2017.
[13] T. S. M. Kumar, N. Rajini, H. Tian, A. V. Rajulu, J. T. W. Jappes, and S. Siengchin, “Development and analysis of biodegradable poly (propylene carbonate)/tamarind nut powder composite films,” International Journal of Polymer Analysis and Characterization, vol. 22, no. 5, pp. 415– 423, 2017.
[14] T. S. M. Kumar, N. Rajini, M. Jawaid, A. V. Rajulu, and J. T. W. Jappes, “Preparation and Properties of cellulose/tamarind nut powder green composites: (Green composite using agricultural waste reinforcement),” Journal of Natural Fibers, vol. 15, no. 1, pp. 11–20, 2018.
[15] S. B. Hassan, V. S. Aigbodion, and S. N. Patrick, “Development of polyester/eggshell particulate composites,” Tribology in Industry, vol. 34, no. 4, pp. 217–225, 2012.
[16] B. Ashok, S. Naresh, K. O. Reddy, K. Madhukar, J. Cai, L. Zhang, and A. V. Rajulu, “Tensile and thermal properties of poly (lactic acid)/eggshell powder composite films,” International Journal of Polymer Analysis and Characterization, vol. 19, no. 3, pp. 245–255, 2014.
[17] B. Ashok, K. O. Reddy, K. Yorseng, N. Rajini, N. Hariram, S. Siengchin, and A. V. Rajulu, “Modification of natural fibers from Thespesia lampas plant by in situ generation of silver nanoparticles in single-step hydrothermal method,” International Journal of Polymer Analysis and Characterization, vol. 23, no. 6, pp. 509–516, 2018.
[18] M. Phuthotham, S. Siengchin, B. Ashok, and A. V. Rajulu, “Modification of egg shell powder with in situ generated copper and cuprous oxide nanoparticles by hydrothermal method,” Materials Research Express, vol. 7, no. 1, 2019 Art. no. 015010, doi: 10.1088/2053-1591/ab5c4c.
[19] L. F. Cabeza, M. M. Taylor, G. L. DiMaio, E. M. Brown, W. N. Marmer, R. Carrio, P. J. Celma, and J. Cot, “Processing of leather waste: Pilot scale studies on chrome shavings. Isolation of potentially valuable protein products and chromium,” Waste Management, vol. 18, no. 3, pp. 211–218, 1998.
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[21] P. Banerjee, S. Madhu, N. C. Babu, and C. Shanthi, “Bio-mimetic mineralization potential of collagen hydrolysate obtained from chromium tanned leather waste,” Materials Science and Engineering, vol. 49, pp. 338–347, 2015.
[22] M. Catalina, J. Cot, A. M. Balu, J. C. Serrano-Ruiz, and R. Luque, “Tailor-made biopolymers from leather waste valorization,” Green Chemistry, vol. 14, no. 2, pp. 308–312, 2012.
[23] H. Lakrafli, S. Tahiri, A. Albizane, M. Bouhria, and M. E. E. Otmani, “Experimental study of thermal conductivity of leather and carpentry wastes,” Construction and Building Materials, vol. 48, pp. 566–574, 2013.
[24] K. Babanas, P. A. Tarantili, and A. G. Andreopoulos, “Plasticized poly (vinyl chloride) filled with waste leather particles,” Journal of Elastomers and Plastics, vol. 33, no. 1, pp. 72–85, 2001.
[25] B. Ramaraj, “Mechanical and thermal properties of ABS and leather waste composites,” Journal of Applied Polymer Science, vol. 101, no. 5, pp. 3062–3066, 2006.
[26] J. D. Ambrósio, A. A. Lucas, H. Otaguro, and L. C. Costa, “Preparation and characterization of poly (vinyl butyral)-leather fiber composites,” Polymer Composites, vol. 32, no. 5, pp. 776–785, 2011.
[27] S. Ponsubbiah, S. Suryanarayana, and S. Gupta, “Composite from leather waste,” International Journal Latest Technology in Engineering, Management and Applied Sciences, vol. 7, no. 3, pp. 77–80, 2018.
[28] T. Ambone, S. Joseph, E. Deenadayalan, S. Mishra, S. Jaisankar, and P. Saravanan, “Polylactic acid (PLA) biocomposites filled with Waste Leather Buff (WLB),” Journal of Polymers and the Environment, vol. 25, pp. 1099–1109, 2016.
[29] K. Sivaprakash, P. Maharaja, S. Pavithra, R. Boopathy, and G. Sekaran, “Preparation of light weight constructional materials from chrome containing buffing dust solid waste generated in leather industry,” Journal of Material Cycles Waste Management, vol. 19, pp. 928–938, 2017.
[30] J. Li, J. M. Zhang, N. Hariram, J. Zhang, B. Ashok, and A. V. Rajulu, “Modification of agricultural waste tamarind fruit shell powder by in situ generation of silver nanoparticles for antibacterial filler applications,” International Journal of Polymer Analysis and Characterization, vol. 24, no. 5, pp. 421–427, 2019.
[31] J. Seetha, U.M. Mallavarapu, P. Akepogu, A. Mesa, V. R. Gollapudi, N. Hariram, and A. V. Rajulu, “Biosynthesis and study of bimetallic copper and silver nanoparticles on cellulose cotton fabrics using Moringa oliefiera leaf extraction as reductant,” Inorganic and Nano-Metal Chemistry, vol. 50, no. 9, pp. 828–835, 2020.
[32] A. V. Rao, B. Ashok, M. U. Mahesh, G. V. Subbareddy, V. C. Sekhar, G. V. Ramanamurthy, and A. V. Rajulu, “Antibacterial cotton fabrics with in situ generated silver and copper bimetallic nanoparticles using red sanders powder extract as reducing agent,” International Journal of Polymer Analysis and Characterization, vol. 24. no. 4, pp. 346–354, 2019.
[33] G. Xia, V. Sadanand, B. Ashok, K. O. Reddy, J. Zhang, and A. V. Rajulu, “Preparation and properties of cellulose/waste leather buff biocomposites,” International Journal of Polymer Analysis and Characterization, vol. 20, no. 8, pp. 693–703, 2015.
[34] S. Joseph, T. S. Ambone, A. V. Salvekar, S. N. Jaisankar, P. Saravanan, and E. Deenadayalan, “Processing and characterization of waste leather based polycaprolactone biocomposites,” Polymer Composites, vol. 38, no. 12, pp. 2889–2897, 2017.
[35] M. Muzamil, N. Khalid, M. D. Aziz, and S. A. Abbas, “Synthesis of silver nanoparticles by silver salt reduction and its characterization,” in IOP Conference Series: Materials Science and Engineering, 2014, vol. 60, no. 1, Art. No. 012034.
[36] G. Sanchez-Olivares, A. Sanchez-Solis, F. Calderas, L. Medina-Torres, O. Manero, A. D. Blasio, and J. Alongi, “Sodium montmorillonite effect on the morphology, thermal, flame retardant and mechanical properties of semi-finished leather,” Applied Clay Science, vol. 102, pp. 254–260, 2014.
[37] S. Ganesh, E. L. Shin, and S. Y. Kim, “Silver nanoparticles incorporated PVC films: Evaluation of structural, thermal, dielectric and catalytic properties,” Polímeros, vol. 29, no. 3, pp. 1–9, 2019.
[38] Z. J. Jiang, C. Y. Liu, and L. W. Sun, “Catalytic properties of silver nanoparticles supported on silica spheres,” Journal of Physical Chemistry B, vol. 109, pp. 1730–1735, 2005.
[39] S. Yan, C. Jiang, J. Guo, Y. Fan, and Y. Zhang, “Synthesis of silver nanoparticles loaded onto polymer-inorganic composite materials and their regulated catalytic activity,” Polymers, vol. 11, no. 3, pp. 1–17, 2019.
[40] M. Mavaei, A. Chahardoli, Y. Shokoohinia, A. Khoshroo, and A. Fattahi, “One-step synthesized silver nanoparticles using isoimperatorin: Evaluation of photocatalytic, and electrochemical activities,” Science Reporter, 2020, Art. no. 1762, doi: 10.1038/s41598-020-58697-x.
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