Lead Ions Removal Using Pineapple Leaf-Based Modified Celluloses

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Published: Feb 23, 2023
DOI: https://doi.org/10.14416/j.asep.2022.05.009
Keywords:
Adsorbent Amide Amidoxime Carboxymethyl Cellulose Pineapple leaf fibers

Main Article Content

Thitiwut Sukprom
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Sarun Chanklang
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Supacharee Roddecha
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Chalida Niamnuy
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Paweena Prapainainar
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Anusorn Seubsai
Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand

Abstract

Pineapple leaves are largely discarded in the harvest area and considered as agricultural waste. Herein, the extracted pineapple leaves fiber was altered with chelating agents to become an adsorbent for lead ions (Pb2+) removal from aqueous solutions. The initial investigation determined that the most appropriate conditions for extracting cellulose fiber from pineapple leaves were stirring at 90–100 °C in 10%w/v NaOH for 1 h. Next, carboxymethyl, amide, and amidoxime were used to modify with the extracted cellulose fiber, denoted as Cell-CMC, Cell-AM, and Cell-AMX, respectively. At pH 6, Cell-CMC, Cell-AM, Cell-AMX, and the extracted cellulose fiber had maximum adsorption potential values of 9.3, 1.5, 3.6, and 6.3 mg g–1, respectively. In the kinetic analysis, Cell-CMC, Cell-AM, and extracted cellulose adsorption behaviors were well represented using a model of pseudo 1st order, while the adsorption behavior of Cell-AMX was best represented using a model of pseudo 2nd order. Further investigation demonstrated that the desorption efficiency of each adsorbent increased as the pH value was lowered from 3, 4, and 6.

Article Details

How to Cite
Sukprom, T., Chanklang, S., Roddecha, S., Niamnuy, C., Prapainainar, P., & Seubsai, A. (2023). Lead Ions Removal Using Pineapple Leaf-Based Modified Celluloses. Applied Science and Engineering Progress, 16(2), 6002. https://doi.org/10.14416/j.asep.2022.05.009
Issue
Vol. 16 No. 2 (2023)
Section
Research Articles

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