Catalyst Screening and Optimization Condition of Green Solvent for BHD Production using Ni-based Catalysts

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Published: Jul 2, 2024
DOI: https://doi.org/10.14416/j.asep.2024.03.002
Keywords:
Dodecane Green solvent Hydrodeoxygenation Methyl laurate

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Patravee Ounsuk
National Center of Excellence for Petroleum, Petrochemicals and Advance Material, Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Sirapat Triampitak
National Center of Excellence for Petroleum, Petrochemicals and Advance Material, Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Jitsinee Leetrakul
National Center of Excellence for Petroleum, Petrochemicals and Advance Material, Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Kandis Sudsakorn
National Center of Excellence for Petroleum, Petrochemicals and Advance Material, Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Anusorn Seubsai
National Center of Excellence for Petroleum, Petrochemicals and Advance Material, Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand
Chaiwat Prapainainar
Department of Chemical Engineering, Faculty of Engineering, King Mongkut's University of Technology North Bangkok, Bangkok, Thailand
Paweena Prapainainar
National Center of Excellence for Petroleum, Petrochemicals and Advance Material, Department of Chemical Engineering, Faculty of Engineering, Kasetsart University, Bangkok, Thailand

Abstract

The high production costs associated with bio-hydrogenated diesel (BHD) have posed a major challenge. Considering this, the present research focused on the production of green solvents at lower pressures as a potential solution. Specifically, the synthesis of various catalysts, namely Ni/γ-Al2O3, Ni/C, NiMo/γ-Al2O3, NiMo/SiO2TiO2, and NiMo/C, was conducted to facilitate the hydrodeoxygenation reaction of methyl laurate into cyclohexane, leading to conversion into dodecane. The resulting green solvent was analyzed using GC-FID and GC-TCD techniques. Among the five catalysts tested, NiMo/C demonstrated superior performance, achieving a conversion rate of 64.61%, selectivity of 62.46%, and yield of 44.98%. The gas analysis conducted using GC-TCD revealed the production of carbon monoxide, methane, and carbon dioxide, aligning with the dodecane pathway theory. Further analysis of the NiMo/C catalyst was conducted using SEM, BET, and XRD techniques, while the Design of Expert program was used to identify more favorable conditions for dodecane production. Through this optimization process, significant improvements were achieved, resulting in a conversion rate of 98.26%, selectivity of 66.82%, and yield of 65.66% at 320 °C and 28 bar, with a reaction time of 6 h.

Article Details

How to Cite
Ounsuk, P., Triampitak, S., Leetrakul, J., Sudsakorn, K., Seubsai, A., Prapainainar, C., & Prapainainar, P. (2024). Catalyst Screening and Optimization Condition of Green Solvent for BHD Production using Ni-based Catalysts. Applied Science and Engineering Progress, 17(3), 7352. https://doi.org/10.14416/j.asep.2024.03.002
Issue
Vol. 17 No. 3 (2024)
Section
Research Articles

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