Effects of Modified Silicon Carbide on The Physical Properties of Bioplastic Blends

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Published: Oct 17, 2024
DOI: https://doi.org/10.14416/j.asep.2024.07.015
Keywords:
Mechanical properties Melt flow rate Morphology Poly(lactic acid) Polybutylene succinate Silicon carbide Thermal properties

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Natkrita Prasoetsopha
Department of Materials Engineering, Rajamangala University of Technology Isan, Nakhon Ratchasima, Thailand
Patcharapon Somdee
Department of Materials Engineering, Rajamangala University of Technology Isan, Nakhon Ratchasima, Thailand
Manjunath Shettar
Department of Mechanical and Industrial Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, India
Manauwar Ali Ansari
Institute of Ceramic and Polymer Engineering, University of Miskolc, Miskolc, Hungary
Pranee Chumsamrong
School of Polymer Engineering, Suranaree University of Technology, Nakhon Ratchasima, Thailand

Abstract

The study’s goal is to improve the physical properties of biodegradable plastics by mixing poly(lactic acid) (PLA), polybutylene succinate (PBS), and silicon carbide (SiC) to make composites that could be used as filaments for 3D printing. Polymer blends and composites were fabricated using an internal mixer. The fraction of SiC was varied from 10 to 40 phr and filled in PLA/PBS blends with a retained ratio of 80/20 wt.%. Then, the mechanical properties, thermal properties, melt flow rate and morphology of PLA/PBS/SiC composites were investigated. Field emission scanning electron microscope images present a uniform dispersion of silane-treated SiC particles throughout the PLA/PBS matrix. The morphology showed better adhesion between PLA/PBS and treated SiC particles. Therefore, this was also the reason for the improvement of Young’s modulus and impact strength when the SiC fraction was increased, which were improved by 33% and 104%, respectively, compared to neat PLA. Furthermore, the melt flow rate increased with an increasing SiC fraction. This might be because adding SiC reduces the viscosity of the composites, which affects the molecular chain movement of the PLA/PBS and the crystallinity of PLA, therefore decreasing the ΔHm of PLA and Xc,PLA. However, Tg and Tm of PLA and PBS remained relatively stable with an increasing fraction of SiC particles.

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How to Cite
Prasoetsopha, N., Somdee, P., Shettar, M., Ansari, M. A., & Chumsamrong, P. (2024). Effects of Modified Silicon Carbide on The Physical Properties of Bioplastic Blends. Applied Science and Engineering Progress, 17(4), 7514. https://doi.org/10.14416/j.asep.2024.07.015
Issue
Vol. 17 No. 4 (2024): Special Issue
Section
Research Articles

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