Influence of Solvents Used for Cassava Rhizome Pretreatment on Fast Pyrolysis Products
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Published:
Aug 31, 2018
Keywords:
Fast pyrolysis solvent effect extractives, bio-oil
Main Article Content
Abstract
Three solvents including water, hexane and acetone were used to pretreat cassava rhizome. The pretreated biomass samples had lower extractives content compared to the non-extracted one. The pretreated samples together with the original biomass were fast pyrolysed in a fluidised bed reactor producing bio-oil, char and gas. The results showed that after extraction with water, hexane and acetone, the yields of total bio-oil, heavy bio-oil and gas increased at the expense of light bio-oil and char yields. A maximum total bio-oil yield of 54 wt% was achieved when using water as solvent. Based on the property analyses, all solvents hardly affect the pH, solids content, ash content and density of bio-oils. However, hexane and acetone could increase the bio-oil heating value. In addition, the flash point, fire point, hydrogen and oxygen contents were increased by the solvent extraction, whereas the carbon content of bio-oil reduced except when using acetone.
Article Details
How to Cite
[1]
ปัตติยะ อ., “Influence of Solvents Used for Cassava Rhizome Pretreatment on Fast Pyrolysis Products”, sej, vol. 13, no. 2, pp. 106–117, Aug. 2018.
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Research Articles
Copyright belongs to Srinakharinwirot University Engineering Journal
References
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[2] S. Sirijanusorn, K. Sriprateep and A. Pattiya, “Pyrolysis of cassava rhizome in a counter-rotating twin screw reactor unit, ” Bioresour. Technol., vol. 139, pp. 343-348, Jul. 2013.
[3] M. Melzer, J. Blin, A. Bensakhria, J. Valette and F. Broust, “Pyrolysis of extractive rich agroindustrial residues, ” J. Anal. Appl. Pyrolysis, vol. 104, pp. 448-460, Nov. 2013.
[4] T. Suchithra, S. Adhikari, H. Ravindran, R. B. Gupta, O. Fasina, M. Tu, S. D. Fernando, “Physiochemical properties of bio-oil produced at various temperatures from pine wood using an auger reactor, ” Journal of Bioresour. Technol., vol. 101, no. 21, pp. 8389-8395, 2010.
[5] R. Fahmi, A. V. Bridgwater, I. Donnison, N. Yates and J. M. Jones, “The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability, ” J. Fuel, vol. 87, no. 7, pp. 1230-1240, 2008.
[6] K. Duanguppama, N. Suwapaet and A. Pattiya, “Fast pyrolysis of contaminated sawdust in a circulating fluidised bed reactor, ” J. Anal. Appl. Pyrolysis, vol. 118, pp. 63-74, Mar. 2016.
[7] B. Pidtasang, P. Udomsap, S. Sukkasi, N. Chollacoop and A. Pattiya, “Influence of alcohol addition on properties of bio-oil produced from fast pyrolysis of eucalyptus bark in a free-fall reactor, ” J. Ind. Eng. Chem., vol. 19, no. 6, pp. 1851-1857, 2013.
[8] K. Raveendran, A. Ganesh and K. C. Khilar, “Influence of mineral matter on biomass pyrolysis characteristics, ” J. Fuel, vol. 74, no. 12, pp. 1812-1822, 1995.
[9] S. W. Kim, B. S. Koo and D. H. Lee, “Catalytic pyrolysis of palm kernel shell waste in a fluidized bed, ” Bioresour. Technol., vol. 167, pp. 425-432, Sep. 2014.
[10] บุญสิริ ปิตตาแสง, สิทธา สุขกสิ, และ อดิศักดิ์ ปัตติยะ, “ผลของอัตราการป้อนชีวมวลต่อผลิตภัณฑ์จากกระบวนการไพโรไลซีสแบบเร็วโดยใช้เตาปฏิกรณ์แบบตกอิสระ, ” วารสารวิทยาศาสตร์และเทคโนโลยีมหาวิทยาลัยมหาสารคาม, ปีที่ 32 ฉบับบที่ 4, หน้า 499-503, กรกฎาคม-สิงหาคม 2556.
[11] P. Kaewpengkrow, D. Atong and V. Sricharoenchaikul, “Catalytic upgrading of pyrolysis vapors from Jatropha wastes using alumina, zirconia and titania based catalysts, ” Bioresour. Technol., vol. 163, pp. 262-269, Jul. 2014.
[12] A. Pattiya, J. O. Titiloye and A. V. Bridgwater, “Evaluation of catalytic pyrolysis of cassava rhizome by principal component analysis, ” J. Fuel, vol. 89, no. 1, pp. 244-253, 2009.
[13] M. Nik-Azar, M. R. Hajaligol, M. Sohrabi and B. Dabir, “Mineral matter effects in rapid pyrolysis of beech wood, ” Fuel Process. Technol., vol. 51, no. 1-2, pp. 7-17, 1997.
[14] X. Guo, S. Wang, K. Wang, Q. Liu and Z. Luo, “Influence of extractives on mechanism of biomass pyrolysis, ” J. Fuel Chem. Technol., vol. 38, no. 1, pp. 42-46, 2010.
[15] S. D. Stefanidis, K. G. Kalogiannis, E. F. Iliopoulou, C. M. Michailof, P. A. Pilavachi, and A. A. Lappas, “A study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose, hemicellulose and lignin, ” J. Anal. Appl. Pyrolysis, vol. 105, pp. 143-150, Jan. 2014
[16] G. Yildiz, F. Ronsse, R. Venderbosch, R. v. Duren, S. R. A. Kersten and W. Prins, “Effect of biomass ash in catalytic fast pyrolysis of pine wood, ” Appl. Catal., B, vol. 168–169, pp. 203-211, Jun. 2015.
[17] ณัฐพันธ์ พรหมสำเภา, นุชิดา สุวแพทย์, และ อดิศักดิ์ ปัตติยะ, “การผลิตไบโอออยล์จากการไพโรไลซีสแบบเร็วของกากเปลือกเมล็ดมะเยาหินและกากเมล็ดปาล์มโดยใช้เครื่องปฏิกรณ์ฟลูอิไดซ์เบดแบบฟอง, ” วารสารวิศวกรรมศาสตร์ มหาวิทยาลัยศรีนครินทรวิโรฒ, ปีที่ 9 ฉบับที่ 2, หน้า 23-32, กรกฎาคม-ธันวาคม 2557.
[18] Y.A. Cengel and M.A. Boles, Thermodynamics: An Engineering Approach, New York: McGraw-Hill, 2006.
[19] S. R. G. Oudenhoven, R. J. M. Westerhof, and S. R. A. Kersten, “Fast pyrolysis of organic acid leached wood, straw, hay and bagasse: Improved oil and sugar yields, ” J. Anal. Appl. Pyrolysis, vol. 116, pp. 253-262, Nov. 2015.
[20] A. Pattiya and S. Suttibak, “Fast pyrolysis of sugarcane residues in a fluidised bed reactor with a hot vapour filter, ” J. Energy Inst., vol. 90, no. 1, pp. 110-119, 2015.
[21] Y. Wang, L. Wu, C. Wang, J. Yu, and Z. Yang, “Investigating the influence of extractives on the oil yield and alkane production obtained from three kinds of biomass via deoxy-liquefaction, ” Bioresour. Technol., vol. 102, no. 14, pp. 7190-7195, 2011.