Fast Pyrolysis of Torrefied Leucaena leucocephala Wood in a Bubbling Fluidised-Bed Reactor

Main Article Content

Adiak Pattiya

Abstract

In this work, torrefaction was proposed as a mean to pretreat Leucaena leucocephala wood prior to fast pyrolysis process. Torrefaction was carried out in a continuous tubular flow reactor to produce torrefied biomass which was subsequently fast pyrolysed in a bubbling fluidised bed reactor to produce bio-oil, char and gas. Five different torrefaction temperatures (240, 260, 280, 300 and 320 C) were applied. The results showed that the torrefied biomass yields were 50-98% depending on the torrefaction severity. After fast pyrolysis process, the bio-oils were separated into two fractions (heavy and light fractions). The total bio-oil yields were reduced from 69% for non-torrefied biomass to 16% for biomass torrefied at 320 C and 64% for biomass torrefied at 240 C. Nevertheless, the heavy bio-oil yield appeared to increase from 30% for non-torrefied biomass to a maximum of 33% for biomass torrefied at 280 C. This corresponds to the increase of energy yield from 34 to 38%. Intriquingly, torrefaction of Leucaena leucocephala at 280 C was also proved to ameliorate the energy efficiency of fast pyrolysis process as up to 65% of energy in biomass could be recovered in the form of liquid and solid biofuels.

Article Details

How to Cite
[1]
A. Pattiya, “Fast Pyrolysis of Torrefied Leucaena leucocephala Wood in a Bubbling Fluidised-Bed Reactor”, sej, vol. 15, no. 2, pp. 81–97, Jun. 2020.
Section
Research Articles

References

A. Pattiya and S. Suttibak, "Fast pyrolysis of sugarcane residues in a fluidised bed reactor with a hot vapour filter," Journal of the Energy Institute, vol. 90, no. 1, pp. 110-119, 2017.

A. Pattiya and S. Suttibak, "Production of bio-oil via fast pyrolysis of agricultural residues from cassava plantations in a fluidised-bed reactor with a hot vapour filtration unit," Journal of Analytical and Applied Pyrolysis, vol. 95, pp. 227-235, 2012.

S. A. Raja, Z. R. Kennedy, B. C. Pillai, and C. L. R. Lee, "Flash pyrolysis of jatropha oil cake in electrically heated fluidized bed reactor," Energy, vol. 35, no. 7, pp. 2819-2823, 2010.

A. V. Bridgwater, "Review of fast pyrolysis of biomass and product upgrading," Biomass and Bioenergy, vol. 38, pp. 68-94, 2012.

A. A. Boateng and C. A. Mullen, "Fast pyrolysis of biomass thermally pretreated by torrefaction," Journal of Analytical and Applied Pyrolysis, vol. 100, pp. 95-102, 2013.

T. Wigley, A. C. K. Yip, and S. Pang, "Pretreating biomass via demineralisation and torrefaction to improve the quality of crude pyrolysis oil," Energy, vol. 109, pp. 481-494, 2016.

R. N. Hilten, R. A. Speir, J. R. Kastner, S. Mani, and K. C. Das, "Effect of Torrefaction on Bio-oil Upgrading over HZSM-5. Part 1: Product Yield, Product Quality, and Catalyst Effectiveness for Benzene, Toluene, Ethylbenzene, and Xylene Production," Energy

& Fuels, vol. 27, no. 2, pp. 830-843, 2013.

R. N. Hilten, R. A. Speir, J. R. Kastner, S. Mani, and K. C. Das, "Effect of Torrefaction on Bio-oil Upgrading over HZSM-5. Part 2: Byproduct Formation and Catalyst Properties and Function," Energy & Fuels, vol. 27, no. 2, pp. 844-856, 2013.

M. Atienza-Martínez, I. Fonts, L. Lázaro, J. Ceamanos, and G. Gea, "Fast pyrolysis of torrefied sewage sludge in a fluidized bed reactor," Chemical Engineering Journal, vol. 259, pp. 467-480, 2015.

D. Chen, K. Cen, X. Jing, J. Gao, C. Li, and Z. Ma, "An approach for upgrading biomass and pyrolysis product quality using a combination of aqueous phase bio-oil washing and torrefaction pretreatment," Bioresource Technology, vol. 233, pp. 150-158, 2017.

D. Chen et al., "Combined pretreatment with torrefaction and washing using torrefaction liquid products to yield upgraded biomass and pyrolysis products," Bioresource Technology, vol. 228, pp. 62-68, 2017.

R. Mahadevan et al., "Effect of torrefaction temperature on lignin macromolecule and product distribution from HZSM-5 catalytic pyrolysis," Journal of Analytical and Applied Pyrolysis, vol. 122, pp. 95-105, 2016.

A. Zheng et al., "Catalytic Fast Pyrolysis of Biomass Pretreated by Torrefaction with Varying Severity," Energy & Fuels, vol. 28, no. 9, pp. 5804-5811, 2014.

B. Mi, Z. Liu, W. Hu, P. Wei, Z. Jiang, and B. Fei, "Investigating pyrolysis and combustion characteristics of torrefied bamboo, torrefied wood and their blends," Bioresource Technology, vol. 209, pp. 50-55, 2016.

W.-H. Chen, K.-M. Lu, S.-H. Liu, C.-M. Tsai, W.-J. Lee, and T.-C. Lin, "Biomass torrefaction characteristics in inert and oxidative atmospheres at various superficial velocities," Bioresource Technology, vol. 146, pp. 152-160, 2013.

S.-W. Du, W.-H. Chen, and J. A. Lucas, "Pretreatment of biomass by torrefaction and carbonization for coal blend used in pulverized coal injection," Bioresource Technology, vol. 161, pp. 333-339, 2014.

S. Zhang, B. Hu, L. Zhang, and Y. Xiong, "Effects of torrefaction on yield and quality of pyrolysis char and its application on preparation of activated carbon," Journal of Analytical and Applied Pyrolysis, vol. 119, pp. 217–223, 2016.

S. Zhang, Q. Dong, T. Chen, and Y. Xiong, "Combination of Light Bio-oil Washing and Torrefaction Pretreatment of Rice Husk: Its Effects on Physicochemical Characteristics and Fast Pyrolysis Behavior," Energy & Fuels, vol. 30, no. 4, pp. 3030-3037, 2016.

S. Zhang, T. Chen, Y. Xiong, and Q. Dong, "Effects of wet torrefaction on the physicochemical properties and pyrolysis product properties of rice husk," Energy Conversion and Management, 2016.

V. Srinivasan, S. Adhikari, S. A. Chattanathan, and S. Park, "Catalytic Pyrolysis of Torrefied Biomass for Hydrocarbons Production," Energy & Fuels, vol. 26, no. 12, pp. 7347-7353, 2012.

W. Cai, A. Fivga, O. Kaario, and R. Liu, "Effects of Torrefaction on the Physicochemical Characteristics of Sawdust and Rice Husk and Their Pyrolysis Behavior by Thermogravimetric Analysis and Pyrolysis–Gas Chromatography/Mass Spectrometry," Energy & Fuels, vol. 31, no. 2, pp. 1544-1554, 2017.

Y. Chen, H. Yang, Q. Yang, H. Hao, B. Zhu, and H. Chen, "Torrefaction of agriculture straws and its application on biomass pyrolysis poly-generation," Bioresource Technology, vol. 156, pp. 70-77, 2014.

E. B. Hassan, I. Elsayed, and A. Eseyin, "Production high yields of aromatic hydrocarbons through catalytic fast pyrolysis of torrefied wood and polystyrene," Fuel, vol. 174, pp. 317-324, 2016.

J. Li, G. Bonvicini, L. Tognotti, W. Yang, and W. Blasiak, "High-temperature rapid devolatilization of biomasses with varying degrees of torrefaction," Fuel, vol. 122, pp. 261-269, 2014.

Z. Yang, M. Sarkar, A. Kumar, J. S. Tumuluru, and R. L. Huhnke, "Effects of torrefaction and densification on switchgrass pyrolysis products," Bioresource Technology, vol. 174, pp. 266-273, 2014.

T. Wigley, A. C. K. Yip, and S. Pang, "A detailed product analysis of bio-oil from fast pyrolysis of demineralised and torrefied biomass," Journal of Analytical and Applied Pyrolysis, vol. 123, pp. 194-203, 2017.

A. Zheng et al., "Effect of torrefaction on structure and fast pyrolysis behavior of corncobs," Bioresource Technology, vol. 128, pp. 370-377, 2013.

J. Meng, A. Moore, D. C. Tilotta, S. S. Kelley, S. Adhikari, and S. Park, "Thermal and storage stability of bio-oil from pyrolysis of torrefied wood," Energy & Fuels, vol. 29, no. 8, pp. 5117-5126, 2015.

Y.-F. Huang, H.-T. Sung, P.-T. Chiueh, and S.-L. Lo, "Microwave torrefaction of sewage sludge and leucaena," Journal of the Taiwan Institute of Chemical Engineers, vol. 70, pp. 236-243, 2017.

S. Sonsupap and A. Pattiya, "Improvement of sugarcane leaves property by torrefaction in a continuous tubular flow reactor," Srinakharinwirot Engineering Journal, vol. 14, no. 1, pp. 106-115, 2019.

S. A. Channiwala and P. P. Parikh, "A unified correlation for estimating HHV of solid, liquid and gaseous fuels," Fuel, vol. 81, no. 8, pp. 1051-1063, 2002.

ECN.NTO (2020, June 1) Phyllis2, database for (treated) biomass, algae, feedstocks for biogas production and biochar [Online]. Available: https://phyllis.nl/

M. Ahiduzzaman and A. K. M. S. Islam, "Energy Yield of Torrefied Rice Husk at Atmospheric Condition," Procedia Engineering, vol. 105, pp. 719-724, 2015.

P. Basu, "Chapter 3 - Pyrolysis and Torrefaction," in Biomass Gasification and PyrolysisBoston: Academic Press, 2010, pp. 65-96.

G. Almeida, J. O. Brito, and P. Perré, "Alterations in energy properties of eucalyptus wood and bark subjected to torrefaction: The potential of mass loss as a synthetic indicator," Bioresource Technology, vol. 101, no. 24, pp. 9778-9784, 2010.

F. Shafizadeh, "Pyrolytic Reactions and Products of Biomass," in Fundamentals of Thermochemical Biomass Conversion. R.P. Overend, T.A. Milne, L.K. Mudge, Ed., Dordrecht: Springer Netherlands, 1985, pp. 183-217.

J. Shankar Tumuluru, S. Sokhansanj, J. R. Hess, C. T. Wright, and R. D. Boardman, "REVIEW: A review on biomass torrefaction process and product properties for energy applications," Industrial Biotechnology, vol. 7, no. 5, pp. 384-401, 2011.

P. Basu, " Biomass Cofiring and Torrefaction," in Biomass Gasification, Pyrolysis and Torrefaction (Second Edition) P. Basu, Ed. Boston: Academic Press, 2013, pp. 353-373.