Wood Substitute Material from Coconut Shell Waste and Green Adhesive 10.32526/ennrj/22/20230182

Main Article Content

Ariya Watcharawitthaya
Natee Srisawat
Siriluk Chiarakorn

Abstract

This research aimed to utilise coconut shell waste as a raw material to produce compressed coconut shell sheets by using environmentally friendly adhesive from epoxidized natural latex and gelatinized tapioca starch. The coconut shells were cut into 1-mm particles and mixed with the adhesive. The mixture was then compressed in a 30×30×0.5 cm mould using a hydraulic compression machine at 5 MPa and 170°C for 5 minutes to form a compressed coconut shell sheet. The different ratios of adhesive to coconut shell particles (30, 40, and 50 g) per 100 g of coconut shell and the different ratios of gelatinized tapioca starch and epoxidized natural rubber (ranging from 1:0, 1:1, 2:1, 3:1, to 4:1 by weight) were examined. Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR) were employed to analyse the morphology and chemical composition of the coconut shell sheets, respectively. The physical and mechanical properties of the compressed coconut shell sheets were evaluated based on the Thai Industrial Standard (TIS) number 876-2547 for flat pressed particleboards. The results demonstrate successful production of compressed coconut shell sheets from coconut shell waste using the environmentally friendly adhesive. ENR played a role in networking between lignin and cellulose. While GTS improved the strength of the composite using hydrogen bonding. The optimal ratio of adhesive to coconut shell particles was 40 g of the green adhesive per 100 g of coconut shell. The optimal ratio of gelatinized tapioca starch to epoxidized natural rubber was 2:1 by weight. The coconut shell sheets produced from this study were uniform in shape, had unique textures, and met industry standards for wood substitute materials.

Article Details

How to Cite
Watcharawitthaya , A. ., Srisawat , N. ., & Chiarakorn, S. (2024). Wood Substitute Material from Coconut Shell Waste and Green Adhesive: 10.32526/ennrj/22/20230182. Environment and Natural Resources Journal, 22(1), 44–54. Retrieved from https://ph02.tci-thaijo.org/index.php/ennrj/article/view/250227
Section
Original Research Articles

References

Akbari S, Gupta A, Khan TA, Jamari SS, Ani NBC, Poddar P. Synthesis and characterization of medium density fiber board by using mixture of natural rubber latex and starch as an adhesive. Journal of the Indian Academy of Wood Science 2014;11(2):109-15.

Agnantopoulou E, Tserki V, Marras S, Philippou J, Panayiotou C. Development of biodegradable composites based on wood waste flour and thermoplastic starch. Journal of Applied Polymer Science 2012;126(1):273-81.

Bhaskar J, Singh VK. Physical and mechanical properties of coconut shell particle reinforced-epoxy composite. Journal of Materials and Environmental Science 2013;4(2):227-32.

Bijarimi M, Ahmad S, Rasid R. Mechanical, thermal and morphological properties of poly (lactic acid) epoxidized natural rubber blends. Journal of Elastomers and Plastics 2014;46(4):338-54.

Bureau of Environmental Health, Department of Health, Ministry of Public Health. Guidelines of Indoor Air Management and Evaluation in Public Building. Bangkok, Thailand: Bureau of Environmental Health, Department of Health, Ministry of Public Health; 2016. (in Thai)

Cai Z, Cadek D, Jindrova M, Kaderabkova A, Kuta A. Physical properties and biodegradability evaluation of vulcanized epoxidized natural rubber/thermoplastic potato starch blends. Materials 2022;15(21):1-16.

Colussi R, Pinto VZ, Halal SLME, Vanier NL, Villanova FA, Silva RM, et al. Structural, morphological, and physicchemical properties of acetylated high-, medium-, and low-amylose rice starches. Carbohydrate Polymer 2014;103:405-13.

Husseinsyah S, Mostapha M. The effect of filler content on properties of coconut shell filled polyester composites. Malaysian Polymer Journal 2011;6(1):87-97.

Ibrahim S, Daik R, Abdullah I. Functionalization of liquid natural rubber via oxidative degradation of natural rubber. Polymers 2014;6:2928-41.

Jiang C, He H, Yao X, Yu P, Zhou L, Jia D. Self-crosslinkable lignin/epoxidized natural rubber composites. Journai of Applied Polymer Science 2014;131(23):1-9.

Junmee S, Sittha H, Chusinuan N, Twishsri W. The study of supply chain model of coconut Production in Prachuap Khiri Khan Chumphon and Surat Thani Provinces. Thai Agricultural Research Journal 2021;39(2):202-14.

Kaden DA, Corinne M, Gunnar DN, Wolkoff P. WHO Guidelines for Indoor Air Quality: Selected Pollutants: Formaldehyde. [Internet]. 2010 [cited 2023 Nov 11]. Available from: https://www.ncbi.nlm.nih.gov/books/NBK138711/.

Lacerda LG, Almerida RR, Demiate IM, Filho MASC, Vasconcelos EC, Woiciechowski AL, et al. Thermoanalytical and starch content evaiuation of cassava bagasse as agro-industrial residue. Brazilian Archives of Biogy and Technology 2009;52:143-50.

Lim JX, Ong TK, Ng CK, Chua IW, Lee YB, Yap ZY, et al. Development of particleboard from green coconut waste. Proceedings of the 15th International Engineering and Computing Research Conference (EURECA 2021); 2021 Jun 30; School of Computer Science and Engineering, Taylor’s University, Malaysia, Subang Jaya, Selangor: Malaysia; 2021.

Naya M, Nakanishi J. Risk assessment of formaldehyde for the general population in Japan. Regulatory Toxicology and Pharmacology 2005;43:232-48.

Olumuyiwa AJ, Isaac TS, Samuel SO. Study of mechanical behavior of coconut shell reinforced polymer matrix composite. Journal of Minerals and Materials Characterization and Engineering 2012;11:774-9.

Owodunni AA, Lamaming J, Hashim R, Folahan O, Taiwo A, Hussin MH, et al. Properties of green particleboard manufactured from coconut fiber using a potato starch based adhesive. BioResources 2020;15(2):2279-92.

Rattanavilai S. Adhesive Development for Rubber Wood from Epoxide Natural Latex. Songkhla, Thailand: Faculty of Engineering Prince of Songkla University; 2007. p. 1-111.

Roumeli E, Papadopoulou E, Pavlidou E, Vourlias G, Bikiaris D, Paraskevopoulos KM, et al. Synthesis, characterization and thermal analysis of urea-formaldehyde/nanoSiO2 resins. Thermochimica Acta 2012;527:33-9.

Strykowski W. Wood - A substitute or a raw material substituted for. Annals of Warsaw University of Life Sciences-SGGW, Forestry and Wood Technology 2013;84:194-200.

Simon JN, Nuthammachot N, Titseesang T, Okpara KE, Techato K. Spatial assessment of para rubber (Hevea brasiliensis) above ground biomass potentials in Songkhla Province, Southern Thailand. Sustainability 2021;13(16):Article No. 9344.

Thuraisingam J, Gupta A, Subramaniam M. Natural rubber latex (NRL) and rice starch as an alternative binder in wood composite industry. Australian Journal of Basic and Applied Sciences 2016;10(17):101-6.

Wronka A, Kowaluk G. The influence of multiple mechanical recycling of particleboards on their selected mechanical and physical properties. Materials 2022;15:1-18.

Yoksan R. Epoxidized natural rubber for adhesive application. Kasetsart Journal (Natural Science). 2008;42:325-32.