Heavy Metals Contamination Assessment Using Pollution Indices for Spring Water in Barwari Bala Villages, Duhok, Kurdistan Region-Iraq 10.32526/ennrj/23/20240328
Main Article Content
Abstract
Regular quality monitoring of drinking water resources is crucial for ensuring a safe drinking water supply for various users. Thus, this study was carried out to assess water safety for human drinking in terms of heavy metal content using pollution indices for spring water in Barwari Bala Villages located in Duhok City, Kurdistan Region of Iraq. Six spring water samples were collected at 10 to 15 day intervals from 10 areas during the summer of 2023. All 60 samples were analyzed in the laboratory to evaluate heavy metal concentrations, including manganese (Mn), chromium (Cr), iron (Fe), zinc (Zn), copper (Cu), cadmium (Cd), and lead (Pb). The overall quality of water was then assessed by utilizing pollution indices, including the degree of contamination (Cd), the heavy metal evaluation index (HEI), and the heavy metal pollution index (HPI). The results revealed that the concentrations of all the selected heavy metals found in spring water samples were lower than the permissible limits based on Iraqi standards, except for Pb in sites SW1 (Kyle Baze), SW2 (Kani Mazne), and SW8 (Derishke), which had higher concentrations of Pb depending on the prescribed limits (10 µg/L). According to metal pollution indices, the values of all the indices were lower than their critical ranges of contamination, indicating that the water of every site was safe for drinking. However, greater concentrations of Pb in spring water at sites SW1, SW2, and SW8 might have an adverse impact on human consumption in the long term. Thus, the treatment of spring water at these sites before utilization is highly recommended to ensure safe water for consumption. Further research is needed to determine the causes and contributing factors behind the rising lead (Pb) levels observed at those locations, as well as to develop appropriate treatment strategies to mitigate contamination.
Article Details

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Published articles are under the copyright of the Environment and Natural Resources Journal effective when the article is accepted for publication thus granting Environment and Natural Resources Journal all rights for the work so that both parties may be protected from the consequences of unauthorized use. Partially or totally publication of an article elsewhere is possible only after the consent from the editors.
References
Abou Zakhem B, Hafez R. Heavy metal pollution index for groundwater quality assessment in Damascus Oasis, Syria. Environmental Earth Sciences 2015;73:6591-600.
Al-Hejuje MM, Hussain NA, Al-Saad HT. Applied heavy metals pollution index (HPI) as a water pollution indicator of Shatt Al-Arab River, Basrah-Iraq. International Journal of Marine Science 2017;7(35):353-60.
Alobaidy AMJ, Abid HS, Maulood BK. Application of water quality index for assessment of Dokan lake ecosystem, Kurdistan Region, Iraq. Journal of Water Resource and Protection 2010;2(9):792-8.
Ameen HA. Spring water quality assessment using water quality index in villages of Barwari Bala, Duhok, Kurdistan Region, Iraq. Applied Water Science 2019;9:Article No. 176.
Ameen HA, Rekani OAO, Barwari VIH. Application of pollution indices for heavy metal contamination assessment in surface water of Duhok Dam (Kurdistan Region, Iraq). Journal of Duhok University 2019;22(1):252-64.
Backman B, Bodiš D, Lahermo P, Rapant S, Tarvainen T. Application of a groundwater contamination index in Finland and Slovakia. Environmental Geology 1998;36:55-64.
Badar MS, Ali S, Daniyal, Akram MW, Faheem K, Khan SU, et al. GIS-based assessment of groundwater vulnerability to heavy metal contamination via water quality pollution indices in urban Aligarh, India. Water Practice and Technology 2024;19(2):419-34.
Banda TD, Kumarasamy MV. Development of water quality indices (WQIs): A review. Polish Journal of Environmental Studies 2020;29(3):2011-21.
Bhardwaj R, Gupta A, Garg JK. Evaluation of heavy metal contamination using environmetrics and indexing approach for River Yamuna, Delhi Stretch, India. Water Science 2017;31(1):52-66.
Brown RM, McClelland NI, Deininger RA, Tozer RG. A water quality index-do we dare. Water and Sewage Works 1970;117(10):339-43.
Brraich OS, Jangu S. Evaluation of water quality pollution indices for heavy metal contamination monitoring in the water of Harike Wetland (Ramsar Site), India. International Journal of Scientific and Research Publications 2015;5(2):1-6.
Central Organization for Standardization and Quality Control (COSQC). Iraq Drinking Water Standard (IQS: 417). Republic of Iraq: Central Organization for Quality Control and Standardization, Council of Ministers; 2001.
Edet AE, Offiong OE. Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo-Odukpani area, Lower Cross River Basin (Southeastern Nigeria). GeoJournal 2002;57(4):295-304.
Gautam RK, Sharma SK, Mahiya S, Chattopadhyaya MC. Contamination of heavy metals in aquatic media: Transport, toxicity and technologies for remediation. In: Sharma S, editor. Heavy Metals in Water: Presence, Removal and Safety. The Royal Society of Chemistry 2014. p. 1-24.
Gurung A, Adhikari S, Chauhan R, Thakuri S, Nakarmi S, Ghale S, et al. Water crises in a water-rich country: case studies from rural watersheds of Nepal’s mid-hills. Water Policy 2019; 21(4):826-47.
Hosseinifard SJ, Mirzaei AM. Hydrochemical characterization of groundwater quality for drinking and agricultural purposes: A case study in Rafsanjan Plain, Iran. Water Qual Expo Health 2015;7(4):531-44.
Issa HM, Alshatteri AH. Assessment of heavy metals contamination in drinking water of Garmian Region, Kurdistan, Iraq. UHD Journal of Science and Technology 2018;2(2):40-53.
Jazza SH, Najim S, Adnan MA. Using heavy metals pollution index (HPI) for assessment quality of drinking water in Maysan Province in Southern East in Iraq. Egyptian Journal of Chemistry 2022;65(2):703-9.
Kamali Maskooni E, Naseri-Rad M, Berndtsson R, Nakagawa K. Use of heavy metal content and modified water quality index to assess groundwater quality in a semiarid area. Water 2020;12:Article No. 4.
Khalid HS, Ali HS, Almashhadany DA. Metalliferous content of drinking water and sediments in storage tanks of some schools in Erbil city, Iraq. Italian Journal of Food Safety 2020;9(3):Article No. 8862.
Kubier A, Wilkin RT, Pichler T. Cadmium in soils and groundwater: A review. Applied Geochemistry 2019;108:Article No. 104388.
Li P. To make the water safer. Exposure and Health 2020; 12(3):337-42.
Li P, Karunanidhi D, Subramani T, Srinivasamoorthy K. Sources and consequences of groundwater contamination. Archives of Environmental Contamination and Toxicology 2021; 80(1):1-10.
Lukhabi DK, Mensah PK, Asare NK, Pulumuka-Kamanga T, Ouma KO. Adapted water quality indices: Limitations and potential for water quality monitoring in Africa. Water 2023;15(9):Article No. 1736.
Majeed OS, Ibraheem AK. Using heavy metals pollution indices for assessment of Tigris River Water within Al-Tarmiya City, Northern Baghdad, Iraq. Ecological Engineering and Environmental Technology 2024;25(3):113-23.
Majid SN, Khwakaram AI, Gado CS, Majeed BK. Pollution status evaluation of some heavy metals along some surface water sources by multivariate data analysis at Sulaimani governorate. Journal of Zankoy Sulaimani 2018;20(1):63-80.
Mohan SV, Nithila P, Reddy SJ. Estimation of heavy metals in drinking water and development of heavy metal pollution index. Journal of Environmental Science and Health. Part A: Environmental Science and Engineering and Toxicology 1996;31(2):283-9.
Patil CA, Nalawade PM, Gadakh BL, Khangar NV. Statistical assessment of groundwater quality using hydrochemical parameters for drinking water of rural areas in Nashik District, Maharashtra, India. Water Science 2022;36(1):136-43.
Postel SL. Entering an era of water scarcity: The challenges ahead. Ecological Applications 2000;10(4):941-8.
Poudel DD, Duex TW. Vanishing springs in Nepalese Mountains: Assessment of water sources, farmers’ perceptions, and climate change adaptation. Mountain Research and Development 2017;37(1):35-46.
Prasad Ahirvar B, Das P, Srivastava V, Kumar M. Perspectives of heavy metal pollution indices for soil, sediment, and water pollution evaluation: An insight. Total Environment Research Themes 2023;6:Article No. 100039.
Prasad B, Bose J. Evaluation of the heavy metal pollution index for surface and spring water near a limestone mining area of the lower Himalayas. Environmental Geology 2001;41:183-8.
Raja V, Lakshmi RV, Sekar CP, Chidambaram S, Neelakantan MA. Health risk assessment of heavy metals in groundwater of Industrial Township Virudhunagar, Tamil Nadu, India. Archives of Environmental Contamination and Toxicology 2021;80(1):144-63.
Reza R, Singh G. Heavy metal contamination and its indexing approach for river water. International Journal of Environmental Science and Technology 2010;7(4):785-92.
Rice EW, Baird RB, Eaton AD, Clesceri LS. Standard Methods for the Examination of Water and Wastewater. 22nd ed. American Public Health Association, American Water Works Association, and Water Environment Federation; 2012.
Saha P, Paul B. Assessment of heavy metal pollution in water resources and their impacts: A review. Journal of Basic and Applied Engineering Research 2016;3(8):671-5.
Saleh HM, Eskander SB, Mahmoud HH, Abdou MI. Groundwater quality and health assessments based on heavy metals and trace elements content in Dakhla Oasis, New Valley Governorate, Egypt. Water Science 2022;36(1):1-12.
Salih FA, Kasem AO, Abdullah TH, Othman NF, Mina MB. Assessment of the quality of drinking water of Halabja City-Iraqi Kurdistan. Kirkuk University Journal/Scientific Studies (KUJSS) 2015;10(3):259-72.
Salim HAM, Abdo HR, Buni FJ, Kareem IM, Najeeb MA, Hussen BA. Estimation and correlation analysis of heavy metals of some well water in Zakho City, Iraq. Science Journal of University of Zakho 2017;5(2):205-9.
Shigut DA, Liknew G, Irge DD, Ahmad T. Assessment of physico-chemical quality of borehole and spring water sources supplied to Robe Town, Oromia region, Ethiopia. Applied Water Science 2017;7:155-64.
Swain CK. Environmental pollution indices: A review on concentration of heavy metals in air, water, and soil near industrialization and urbanisation. Discover Environment 2024;2:Article No. 5.
Terry PA, Stone W. Biosorption of cadmium and copper contaminated water by Scenedesmus abundans. Chemosphere 2002;47(3):249-55.
Tran TT, Liem ND, Hieu HH, Tam HT, Van Mong N, Yen NTM, et al. Assessment of long-term surface water quality in Mekong River Estuaries using a comprehensive water pollution index. Environment and Natural Resources Journal 2023;21(6):524-33.
Wang L, Zhang Q, Wang H. Rapid urbanization has changed the driving factors of groundwater chemical evolution in the large groundwater depression funnel area of Northern China. Water 2023;15(16):Article No. 2917.
World Health Organization (WHO). Guidelines for Drinking-Water Quality: First Addendum. 4th ed. Geneva: WHO; 2017.