Electrochemical study of hemin/polypyrole incorporated on carbon paste electrode for voltammetric ascorbic acid determination

Main Article Content

ภัทรานิตฐ์ ทองเทพ
สมพร มูลมั่งมี
ฉัตรชัย พลเชี่ยว

Abstract

This research, hemin/polypyrrole film was incorporated onto a carbon paste electrode by electro-deposition method. The modified electrode was electrochemical characterized in order to ascorbic acid determination. The hemin at electrode surface acts as the mediator to enhance electron transfer from ascorbic acid to an electrode. The anodic peak current observed in cyclic voltammetry was linearity dependent on the ascorbic acid concentration of 44 to 44,000 mg/L. The detection limit of the method is 0.5 mg/L. The developed method presents high accuracy, good precision and comfortable technique for ascorbic acid determination in various sample applications.

Article Details

How to Cite
1.
ทองเทพ ภ, มูลมั่งมี ส, พลเชี่ยว ฉ. Electrochemical study of hemin/polypyrole incorporated on carbon paste electrode for voltammetric ascorbic acid determination. Prog Appl Sci Tech. [Internet]. 2014 Dec. 23 [cited 2024 May 5];4(2):25-32. Available from: https://ph02.tci-thaijo.org/index.php/past/article/view/243213
Section
Pure and Applied Chemistry

References

S.J. Padayatty, A. Katz, Y. Wang, P. Eck, O. Kwon, J.H. Lee, S. Chen, C. Corpe, A. Dutta, S.K. Dutta, M. Levine, Vitamin C as an antioxidant: evaluation of its role in disease prevention, J. Am. Coll. Nutr. 22 (2003): 18-35.

P. M. Bradshaw, B. Celia, A. C. Clark, P. D. Prenzler and R. S. Geoffrey, Ascorbic acid: A review of its chemistry and reactivity in relation to a wine environment, Crit. Rev. Food Sci. Nutr. 51 (2011): 479-498.

G.S. Deshmukh, M.G. Bapat, Determination of ascorbic acid by potassium iodate, Anal. Chem. 145 (1955): 254-256.

H. Iwase, I. Ono, Determination of ascorbic acid in food by column liquid chromatography with electrochemical detection using eluent for pre-run sample stabilization, J. Chromatogr. A 806 (1998): 361-364.

S. Vermeir, M.L. Hertog, A. Schenk, K. Beullens, B.M. Nicolai, J. Lammertyn, Evaluation and optimization of high-throughput enzymatic assays for fast l-ascorbic acid quantification in fruit and vegetables, Anal. Chim. Acta 618 (2008): 94-101.

L. Nova kova, P. Solich, D. Solichova, HPLC methods for simultaneous determination of ascorbic and dehydroascorbic acids, Trend Anal Chem. 27, (2008): 942-958.

C.S. Erdurak-Kilic, B. Uslu, B. Dogan, U. Ozgen, S.A. Ozkan, M. Coskun, Anodic voltammetric behavior of ascorbic acid and its selective determination in pharmaceutical dosage forms and some Rosa species of Turkey, J. Anal. Chem. 61 (2006): 1113-1120.

ฉ. พลเชี่ยว. การพัฒนาขั้วไฟฟ้าคาร์บอนเพสด้วยเฮมีน/พอลิไพโรล สำหรับการตรวจวัดปริมาณไนไตรท์ในน้้าดื่ม. ว วิทย เทคโน มทร ธัญบุรี. 3 (2) (2013): 38–44.

S. F. Peteua, T. Bosea, M. Bayachou, Polymerized hemin as an electrocatalytic platform for peroxynitrite’s oxidation and detection, Electrochim Acta. 780 (2013) 81–88.