SiO2-TiO2 NANOCOMPOSITE WITH SILICA FROM THE RICE HUSK FOR DECOMPOSITION OF METHYLENE BLUE

Authors

  • Patcharaporn Pimchan Department of Chemistry, Faculty of Science and Technology, Rajabhat Maha Sarakham University.

Keywords:

Nanocomposite, Adsorption, Photocatalytic, Rice Husk, Titanium Dioxide

Abstract

The study of SiO2-TiO2 nanocomposite (SiO2-TiO2) with silica from the rice husk was intended to be enhanced the photocatalytic of titanium dioxide (TiO2) for decomposition of methylene blue. The morphology of the hybrid was characterized by XRD, FT-IR and SEM. The photocatalytic activity was study by using the degradation of methylene blue with spectrophotometry technique. From the study found that, Silica (SiO2) can be extracted from the rice husk at 6.62%. After prepared to SiO2-TiO2 composite, the hybrid presented the spherical particles at diameter of about 0.5 μm. The SiO2-TiO2 nanocomposite showed the photocatalytic activity at 91.65 % in sunlight at 660 min, while the pure titanium dioxide revealed the photocatalytic activity at 48.45 % in sunlight at the same time. The photocatalytic activity of SiO2-TiO2 nanocomposites was higher than pure titanium dioxide (TiO2). Indicating that the mesoporous silica (SiO2) can be improved the photocatalytic efficiency of titanium dioxide. It is related to the structure and particle sizes of the titanium dioxide (TiO2) as well as adsorption of methylene blue of silica (SiO2) were resulting photocatalytic activity in better.
The prepared nanocomposite material was effective in degrading the color of methylene blue under sunlight.

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References

Assawasaengrat, P., and Ponpo, P. (2012). Adsorption of dye by adsorbent derived from rice husk. In Research Report. Bangkok: King Mongkut's Institute of Technology Ladkrabang.

Chumee, J. (2011). Preparation of pure silica from rice husk and using as a silica source for synthesis of zeolite. Bangkok: Suan Sunandha Rajabhat University.

Tipsotnaiyana, N. (2014). Synthesized nano-silica from rice husk to Improve printing quality of flexography on white kraft paper. [Unpublished doctoral dissertation]. Kasetsart University.

Harrison, J. A., Frings, P. J., Beusen, A. H. W., Conley, D. J., and McCrackin, M. L. (2012). Global importance patterns and controls of dissolved silica retention in lakes and reservoirs. Global Biogeochemical Cycles, 26(2), 1-12.

Juang, L.-C., Wang, C.-C., and Lee, C.-K. (2006). Adsorption of basic dyes onto MCM-41. Chemosphere, 64(11), 1920-1928.

Chareonpanich, M., Nanta-ngern, A., and Limtrakul, J. (2007). Short-period synthesis of ordered mesoporous silica SBA-15 using ultrasonic technique. Materials Letters, 61, 5153-5156.

Ding, H., Wang, Y. B., Liang, N., and Wang, B. K. (2011). Activation of Natural Zeolite and its Adsorption Property. Advanced Materials Research, 178, 3-7.

Teketel, S., Svelle, S., Lillerud, K. P., and Olsbye, U. (2009). Shape-Selective conversion of methanol to hydrocarbons over 10-ring unidirectional-channel acidic H-ZSM-22. ChemCatChem, 1(1), 78-81.

Phomcham, A., and Makla, V. (2014). Properties of titanium dioxide and silicon dioxide composite nanostructure by hydrothermal method. Journal of Graduate School, Pitchayatat, 9(1), 143-148.

Limkhajonkiat, K., and Tangkananurak, K. (2021). Treatment of reactive dyes in aqueous solution by TiO2-photocatalytic degradation process. Srinakharinwirot University (Journal of Science and Technology), 13(25), 1-12.

Bakar, R. A., Yahya, R., and Gan, S. N. (2016). Production of High Purity Amorphous Silica from Rice Husk. Procedia Chem, 19, 189-195.

Nakamura, K. J., Ide, Y., and Ogawa, M. (2011). Molecular recognitive photocatalytic decomposition on mesoporous silica coated TiO2 particle. Materials Letters, 65(1), 24-26.

Kow, K.-W., Yusoff, R., Aziz, A. R. A., and Abdullah, E. C. (2014). From bamboo leaf to aerogel: Preparation of water glass as a precursor. Journal of Non-Crystalline Solids, 386, 76-84.

Norsuraya, S., Fazlena, H., and Norhasyimi, R. (2016). Sugarcane Bagasse as a Renewable Source of Silica to synthesize Santa Barbara Amorphous-15 (SBA-15). Procedia Engineering, 148, 839-846.

Munasir, Triwikantoro, Zainuri, M., and Darminto. (2015). Synthesis of SiO2 nanopoweders containing quartz and cristobalite phases from silica sands. Materials Science-Poland, 33(1), 47-55.

Liu, H., Deng, L., Sun, S., Li, J., and Zhu, Z. (2015). Titanium dioxide encapsulation of supported Ag nanoparticles on the porous silica bead for increased photocatalytic activity. Applied Surface Science, 326, 82-90.

Klapiszewski, Ł., Siwińska-Stefańska, K., and Kołodyńska, D. (2017). Preparation and characterization of novel TiO2/linin and TiO2- SiO2/lignin hybrids and their use as functional biosorbents for Pb(II). Chemical Engineering Journal, 314, 169-181.

Liang, Y., Ouyang, J., Wang, H., Wang, W., Chui, P., and Sun, K. (2012). Synthesis and characterization of core–shell structured SiO2@YVO4: Yb3+, Er3+ microspheres. Applied Surface Science, 258, 3689-3694.

Bernal, Y. P., Alvarado, J., Juárez, R. L., Rojas, M. Á. M., de Vasconcelos, E. A., de Azevedo, W. M., Iniesta, S. A., and Cab, J. V. (2019). Synthesis and characterization of MCM-41 powder and its deposition by spin-coating. Optik, 185, 429-440.

Haroun, A. A., and Youssef, A. M. (2011). Synthesis and electrical conductivity evaluation of novel hybrid poly (methylmethacrylate)/titanium dioxide nanowires. Synthetic Metals, 161, 2063-2069.

Kambara, K., Shimura, N., and Makoto, M. (2007). Larger Scale Syntheses of Surfactant-Templated Nanoporous Silica Spherical Particles by the Stöber Method. Journal of the Ceramic Society of Japan, 115(5), 315-318.

Kim, Y. N., Shao, G. N., Jeon, S. J., Imran, S. M., Sarawade, P. B., and Kim, H. T. (2013). Sol–gel synthesis of sodium silicate and titanium oxychloride based TiO2–SiO2 aerogels and their photocatalytic property under UV irradiation. Chemical Engineering Journal, 231, 502-511.

Jurkvon, T. Chiarakorn, S., and Chuangchote, S. (2015). Effect of Acid Treated Carbon Nanotube on Photocatalysis of Titanium Dioxide. In Proceeding The 34th national graduate research conference. (pp. 415-424). Khon Kaen: Khon Kaen University.

Kahapana, C., and Phowan, N. (2020). A Study on Adsorption Efficiency of Methylene Blue Dye using Adsorbent Material Prepared from Water Hyacinth. SWU Engineering Journal, 15(2), 58-70.

Sangchay, W. (2016). Photocatalytic Properties of Fe-doped TiO2 Thin Films Coated on Glass Fiber. Industrial Technology Lampang Rajabhat University Journal, 9(1), 87-99.

Werapun, A., khunthongyim, N., Kongprasit, S., and Weerapan, W. (2018). Photodegradation of Methylene Blue with TiO2 and TiO2/SiO2. Journal of Science and Technology, Ubon Ratchathani University, 20(1), 126-134.

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Published

2023-11-07

How to Cite

Pimchan, P. (2023). SiO2-TiO2 NANOCOMPOSITE WITH SILICA FROM THE RICE HUSK FOR DECOMPOSITION OF METHYLENE BLUE . Srinakharinwirot University Journal of Sciences and Technology, 15(30, July-December), 1–12, Article 251595. Retrieved from https://ph02.tci-thaijo.org/index.php/swujournal/article/view/251595