Production of red palm oil and red palm fats by vacuum frying sterilization and multi-step fractionation
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Abstract
The question on health impact of the refining palm oil has driven the oil palm producers in Thailand toward developing the wellness products that are in high demand in the future. Red palm oil (RPO) which is rich in carotenoids and vitamin E catches attention. However, production of RPO by the current steam sterilization method has negative impact on environment and requires high capital investment, while the cost-saving dry sterilization method delivers a low-quality product. To develop the effective RPO processing method suitable for the small and medium-size enterprises (SMEs), the vacuum frying method was studied. The whole production steps consist of vacuum frying sterilization, acid degumming, neutralization, and then multi-step fractionation. The steam sterilization method was compared by using the same arrangement step except the sterilizing procedure. Sterilization by the vacuum fryer was controlled at 80 °C, -400 to -720 mmHg. Results showed that the optimal vacuum frying time was 90 min. The fractionation temperatures of the vacuum frying method were 34 °C, 27 °C and 17 °C, whereas those of the steam sterilized method were 34 °C, 25 °C and 15 °C. Quality of RPOs produced from both methods were within the edible oil standard. The vacuum frying method produced the RPO with 0.17% free fatty acids, 6.65 meq.O2/kg peroxide value, 620 mg/kg carotenoids, 835 mg/kg vitamin E and 61.31% yield. The main advantage in term of quality of the vacuum frying method lies mainly in improving yield and oil odor, which is a sensory characteristic that play an important role in consumer acceptance of the product. The red palm fats obtained from the multi-step fractionation provided a wide range of fats suitable for different applications. Therefore, the vacuum frying could be regarded as the sustainable process technology appropriated for the SMEs.
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References
Tan, C.H.; Lee, C.J.; Tan, S.N.; Poon, D.T.S.; Chong, C.Y.E.; Pui, L.P. Red palm oil: A review on processing, health benefits and its application in food. Journal of Oleo Science 2021, 70(9) 1201-1210. https://doi.org/10.5650/jos.ess21108.
Sumarna, D.; Sumarlan, S.H.; Wijaya, S.; Hidayat, N. Processing of olein fraction red palm oil with minimal refining method and optimization of deodorization process. Advances in Biological Sciences Research 2021, 17, 167-175. https://doi.org/10.2991/absr.k.220102.026.
Hadi, S.; Ahmad, D.; Akande, F.B. Determination of the bruise indexes of oil palm fruits. Journal of Food Engineering 2009, 95(2), 322-326. https://doi.org/10.1016/j.jfoodeng.2009.05.010.
Pande, G.; Akoh, C.C.; Lai, O.M. Food uses of palm oil and its components. Palm oil: Production, Processing, Characterization, and Uses, AOCS Press, Urbana. 2012, 561-586. https://doi.org/10.1016/B978-0-9818936-9-3.50022-8.
Mohd Omar, A.K.; Tengku Norsalwani, T.L.; Asmah, M.S.; Badrulhisham, Z.Y.; Easa, A.M.; Omar, F.M.; Hossain, M.S.; Zuknik, M.H.; Nik Norulaini, N.A. Implementation of the supercritical carbon dioxide technology in oil palm fresh fruits bunch sterilization: A review. Journal of CO2 Utilization 2018, 25, 205–215. https://doi.org/10.1016/j.jcou.2018.03.021.
Okogbenin, O.B.; Okogbenin, E.A.; Okunwaye, T.; Odigie, E.E.; Ojieabu, A. Isolation of food pathogens from freshly milled palm oil and the effect of sterilization on oil quality parameters. Journal of Food Security 2014, 2(2), 65-71. https://doi.org/10.12691/jfs-2-2-4.
Ayustaningwarno, F.; Dekker, M.; Fogliano, V.; Verkerk, R. Effect of vacuum frying on quality attributes of fruits. Food Engineering Reviews 2018, 10(3), 154–164. https://doi.org/10.1007/s12393-018-9178-x.
Shi-Cheng, T.; Teck-Kim, T.; Yee-Ying, L. A review on the fundamentals of palm oil fractionation: Processing conditions and seeding agents. European Journal of Lipid Science and Technology 2021, 123(12), https://doi.org/10.1002/ejlt.202100132.
Singha, K.; Wiesenbornb, D.P.; Tostensonb, K.; Kangas, N. Influence of moisture content and cooking on screw pressing of crambe seed. Journal of the American Oil Chemists' Society 2002, 79(2), 165-170.
Ribeiro, H.S.; Chu, B.S.; Ichikawa, S.; Nakajima, M. Preparation of nanodispersions containing β-carotene by solvent displacement method. Food Hydrocolloids 2008, 22(1), 12-17. https://doi.org/10.1016/j.foodhyd.2007.04.009.
AOAC. Official Methods of Analysis, 20th Ed.; The Association of Official Analytical Chemists, Maryland, USA. 2000.
AOAC. Official Methods of Analysis, 19th Ed.; The Association of Official Analytical Chemists, Washington DC, USA. 2016.
Shammugasamy, B.; Ramakrishnan, Y.; Manan, F.; Muhammad, K. Rapid reversed-phase chromatographic method for determination of eight vitamin E isomers and γ-oryzanols in rice bran and rice bran oil. Food Analytical Methods 2015, 8(3), 649–655, http://dx.doi.org/10.1007/s12161-014-9929-0.
Rakprasoot, J. Production and properties of fractionated products of red palm oil and applications as functional ingredients in padthai sauce, chocolate, and nile tilapia fish (Oreochromis niloticus) feed [Doctoral Dissertation]. Thailand: Chiang Mai University. 2022.
Chompoo, M.; Damrongwattanakool, D.; Raviyan, P. Properties of healthy oil formulated from red palm, rice bran and sesame oils. Songklanakarin journal of science and technology 2019, 41(2), 450-458. https://doi.org/10.14456/sjst-psu.2019.56.
Pootao, S.; Kanjanapongkul, K. Effects of ohmic pretreatment on crude palm oil yield and key qualities. Journal of Food Engineering 2016, 190, 94-100. doi.org/10.1016/j.jfoodeng.2016.06.021.
Department of Standards Malaysia, MS816: Palm olein specification (Second revision), Malaysian Standard, Malasia, 2007.
Kellens, M.; Gibon, V.; Hendrix, M.; Grey, W.D. Palm oil fractionation. European Journal of Lipid Science and Technology 2007, 109(4), 336–349. https://doi.org/10.1002/ejlt.200600309.
Foubert, I.; Van de Walle, D.; Dewettinck, K. Physical properties: Strutural and physical characteristics. In: Gunstone, F.D.; Harwood, J.L.; Dijkstra, A.J. (Eds.), The lipid handbook, CRC Press. New York, 2007, 471-534.
Kellens, M.; Calliauw, G.; Hendrix, M. Continuous fractionation of triglyceride oils. U.S. Patent Application Publication, 2013, 1-8.
Tan, C.H.; Ghazali, H.M.; Kuntom A,; Tan, C.P.; Ariffin, A.A. Extraction and physicochemical properties of low free fatty acids crude palm oil. Food Chemistry 2009, 113(2), 645–650. https://doi.org/10.1016/j.foodchem.2008.07.052.
Thompson-Morrison, H.; Gaw, S.; Robinson, B. An assessment of trace element accumulation in palm oil production. Sustainability 2022, 14(8), 4553. https://doi.org/10.3390/su14084553.
Szydłowska-Czerniak, A.; Trokowski, K.; Karlovits, G.; Szłyk, E. Spectroscopic determination of metals in palm oils from different stages of the technological process. Journal of Agricultural and Food Chemistry 2013, 61(9), 2276–2283. https://doi.org/10.1021/jf305094s.
Gibon, V.; Ayala, V. J.; Dijckmans, P.; Maes, J.; De Greyt, W. Future prospects for palm oil refining and modifications, Oilseeds Fats. Crops and Lipids 2009, 16(4), 193-200. https://doi.org/10.1051/ocl.2009.0268.
Szydlowska-Czerniak, A. MIR spectroscopy and partial least-squares regression for determination of phospholipids in rapeseed oils at various stages of technological process. Food Chemistry 2007, 105(3), 1179-1187. https://doi.org/10.1016/j.foodchem.2007.02.038.
Rakprasoot, J.; Tiampakdee, A.; Raviyan, P. Processing of red palm oil by modified acid method. Food Agricultural Sciences and Technology 2023, 9(2), 11-22.
Choudhary, M.; Grover, K. Fruit oils: chemistry and functionality, Palm (Elaeis Guineensis Jacq.) oil. Springer, Denmark, 2019, 789–802.
Loganathan, R.; Selvaduray, K.R.; Nesaretnam, K.; Radhakrishnan, A.K. Health promoting effects of phytonutrients found in palm oil, Malaysian Journal of Nutrition 2010, 16(2), 309-322.
Bogacz-Radomska, L.; Harasym, J. β-Carotene properties and production methods. Food Qual. Saf 2018, 2(2), 69–74. https://doi.org/10.1093/fqsafe/fyy004.
Rodriguez-Amaya, D.B. A guide to carotenoid analysis in foods. ILSI Press, Washington, D.C., USA, 2001.
Vitamin E-Acetate; MSDS No. 7695-91-2 [Online]; BASF, Thailand, Mar 27, 2023. https://download.basf.com/p1/000000000030804037_SDS_GEN_US/en_US/Vitamin_E_Acetate_Food_30804037_SDS_GEN_US_en_1-1.pdf, 2022 (accessed Apr 25, 2024).
Boon, C.M.; Ng, M.H.; Choo, Y.M.; Mok, S.L. Super, red palm and palm oleins improve the blood pressure, heart size, aortic media thickness and lipid profile in spontaneously hypertensive rats. Public Library of Science One 2013, 8(2), 1-12. https://doi.org/10.1371/journal.pone.0055908.
El-Hadad, N.; Abou-Gharbia, H.A.; El-Aal, M.H.A.; Youssef, M.M. Red palm olein: characterization and utilization in formulating novel functional biscuits. Journal of the American Oil Chemists' Society 2010, 87(3), 295–304. https://doi.org/10.1007/s11746-009-1497-x.
Bonnie, T.Y.P.; Choo, Y.M. Valuable minor constituents of commercial red palm olein: carotenoids, vitamin E, ubiquinones and sterols. Journal of Oil Palm Research 2000, 12(1), 97–108.
Dueik, V.; Bouchon, P. Development of healthy low-fat snacks: understanding the mechanisms of quality changes during atmospheric vacuum frying. Food Reviews International 2011, 27(4), 408-432. https://doi.org/10.1080/87559129.2011.563638.
Kita, A.; Lisinska, G.; Golubowska, G. The effect of oil and frying temperatures on the texture and fat content of potato crisps. Food Chemistry 2007, 102(1), 1-5. https://doi.org/10.1016/j.foodchem.2005.08.038.