A Simple Solid-solid Reaction for the Synthesis of Lead sulfide-montmorillonite Hybrid
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Published:
May 21, 2019
Keywords:
Montmorillonite Solid-solid Reaction Lead Sulfide Optical Properties
Main Article Content
Abstract
The hybrid materials of lead sulfide with montmorillonite were synthesized by a solid-solid reaction between lead-exchanged montmorillonite and sodium sulfide at ambient condition. The hybrids were characterized by powder X-ray diffraction (XRD), thermogravimetric-differential thermal analysis (TG-DTA). The basal spacing of heat-treated lead sulfide-montmorillonite-sodium sulfide (200oC) was 1.20 nm. The formation of lead sulfide in the hybrid confirmed by the non-resolved absorption band and absorption onset at 328 and 508 nm, respectively for heat-treated lead sulfide-montmorillonite-sodium sulfide. The dramatic blue-shifted in the absorption onset relative to that of bulk was observed.The heat treated lead sulfide-montmorillonite-sodium sulfide showed an emission peak at 367 nm. The removal of adsorbed water resulted in the increasing intensity of the hybrid.
Article Details
How to Cite
[1]
A. Baoulan and S. Intachai, “A Simple Solid-solid Reaction for the Synthesis of Lead sulfide-montmorillonite Hybrid”, RMUTP Sci J, vol. 13, no. 1, pp. 51–62, May 2019.
Section
บทความวิจัย (Research Articles)
ลิขสิทธ์ ของมหาวิทยาลัยเทคโนโลยีราชมงคลพระนคร
References
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[2] T. Trindade, “Nanocrystalline semiconductors: synthesis, properties, and perspectives,” Chemistry of Materials, vol. 13, pp. 3843-3858, 2001.
[3] T.K. Singh and S.K. Sharma, “Lead sulphide-doped silica xerogel by sol-gel technique,” Defence Science Journal, vol. 46, pp. 105-107, 1996.
[4] J. Li and J.Z. Zhang, “Optical properties and applications of hybrid semiconductor nanocrystals,” Coordination Chemistry Reviews, vol. 253, 3015-3041, 2009.
[5] A.P. Alivisatos, “Perspectives on the physical chemistry of semiconductor nanocrystals,” Journal of Physical Chemistry, vol. 100, pp. 13226-13239, 1996.
[6] Y.-P. Sun, R. Guduru, F. Lin and T. Whiteside, “Preparation of nanoscale semiconductors through the rapid expansion of supercritical solution (RESS) into liquid solution,” Industrial and Engineering Chemistry Research, vol. 39, pp. 4663-4669, 2000.
[7] S. Chen, L.A. Truax and J.M. Sommers, “Alkanethiolate-protected PbS nanoclusters: synthesis, spectroscopic and electrochemical studies,” Chemistry of Materials, vol. 12, pp. 3864-3870, 2000.
[8] A.S. Obaid, M.A. Mahdi and Z. Hassan, “Growth of nanocrystalline PbS thin films by solid-vapor deposition,” Advanced Materials Research, vol. 620, pp. 1-6, 2013.
[9] S. Seghaier, N. Kamoun, R. Brini and A.B. Amara, “Structural and optical properties of PbS thin films deposited by chemical bath deposition,” Materials Chemistry and Physics, vol. 97, pp. 71-80, 2006.
[10] F. Gao, Q. Lu, X. Liu, Y. Yan and D. Zhao, “Controlled synthesis of semiconductor PbS nanocrystals and nanowires inside mesoporous silica SBA-15 phase,” Nano Letters, vol. 1 pp. 743-748, 2001.
[11] M. Flores-Acosta, M. Sotelo-Lerma, H. Arizpe-Chávez, F.F. Castillón-Barraza and R. Ramírez-Bon, “Excitonic absorption of spherical PbS nanoparticles in zeolite A,” Solid State Communications, vol. 128, pp. 407-411, 2003.
[12] W. Chen, Z. Wang, Z. Lin, J. Qian and L. Lin, “New observation on the formation of PbS clusters in zeolite-Y,” Applied Physics Letters, vol. 68, pp. 1990-1992, 1996.
[13] K. Moller, T. Bein, N. Herron, W. Mahler and Y. Wang, “Encapsulation of lead sulfide molecular clusters into solid matrices, structural analysis with X-ray absorption spectroscopy.” Inorganic Chemistry, vol. 28, pp. 2914-2919, 1989.
[14] C. Leiggener and G. Calzaferri, “Synthesis and luminescence properties of Ag2S and PbS clusters in zeolite A,” Chemistry A European Journal, vol. 11, pp. 7191-7198, 2005.
[15] L. Jankovič, K. Dimos, J. Bujdk, I. Koutselas, J. Madejová, D. Gournis, M.A. Karakassides and P. Komadel, Synthesis and characterization of low dimensional ZnS- and PbS-semiconductor particles on montmorillonite template,” Physical Chemistry Chemical Physics., vol. 12, pp. 14236-14244, 2010.
[16] M. Ogawa, T. Kuroda and K. Kato, “Intercalation of 2,2-bipyridine and complex formation in the interlayer space of montmorillonite by solid-solid reactions,” Inorganic Chemistry, vol. 30, pp. 584-585, 1991.
[17] M. Ogawa, Y. Nagafusa, K. Kuroda and C. Kato, “Solid-state intercalation of crylamide into smectites and Na-taeniolite,” Applied Clay Science, vol. 7, pp. 291-302, 1992.
[18] M. Ogawa, T. Aono, K. Kuroda and C. Kato,“Photophysical probe study of alkylammonium-montmoillonites.” Langmuir, vol. 9, pp. 1529-1533, 1993.
[19] M. Ogawa, K. Saito and M. Sohmiya, “A controlled spatial distribution of functional units in the two dimensional nanospace of layered silicates and titanates. Dalton Trans, vol. 43, pp. 10340-10354, 2014.
[20] S. Miao, Z. Liu, B. Han, H. Yang, Z. Miao and Z. Sun, “Synthesis and characterization of ZnS-montmorillonite nanocomposites and their application for degrading eosin B,” Journal of Colloid and Interface Science, vol. 301, pp. 116-122, 2006.
[21] C. Ooka, S. Akita, Y. Ohashi, T. Horiuchi, K. Sukuki, S.-I. Komai, H. Yoshida and T. Hattori, “Crystallization of hydrothermally treated TiO2 pillars in pillared montmorillonite for improvement of the photocatalytic activity,” Journal of Materials Chemistry, vol. 9, pp. 2943-2952, 1999.
[22] Z. Han, H. Zhu, S.R. Bulcock and S.P. Ringer, “One-step synthesis and structural features of CdS/montmorillonite nanocomposites,” Journal of Physic Chemistry B, vol. 109, pp. 2673-2678, 2005.
[23] N. Khaorapapong, N. Khumchoo and M. Ogawa, “Preparation of zinc oxide-montmorillonite hybrids,” Materials Letters, vol. 65, pp. 657-660, 2011.
[24] N. Khaorapapong, N. Khumchoo and M. Ogawa, “Preparation of copper oxide in smectites,” Applied Clay Science, vol. 104, pp. 238-244, 2015.
[25] A. Ontam, N. Khaorapapong and M. Ogawa, “An incorporation of cadmium selenide at organophillic surface of clay mineral,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 411, pp. 27-33, 2012.
[26] A. Ontam, N. Khaorapapong and M. Ogawa, “Immobilization of cadmium telluride nanoparticles on the surface of hexadecyltrimethylammonium-montmorillonite.” Journal of Materials Chemistry, vol. 22, pp. 20001-20007, 2012.
[27] N. Khaorapapong, A. Ontam, S. Yongme and M. Ogawa, “Solid-state intercalation and in situ formation of cadmium sulfide in the interlayer space of montmorillonite,” Journal of Physics and Chemistry of Solids, vol. 69, pp. 1107-1111, 2008.
[28] N. Khaorapapong, A. Ontam, J. Khemprasit and M. Ogawa, “Formation of MnS- and NiS-montmorillonites by solid-solid reactions,” Applied Clay Science, vol. 43. pp. 238-242, 2009.
[29] N. Khaorapapong, A. Ontam and M. Ogawa, “Very slow formation of copper sulfide and cobalt sulfide nanoparticles in montmorillonite,” Applied Clay Science, vol. 51, pp. 182-186, 2011.
[30] D.M. Clementz, T.J. Pinnavain and M.M. Mortland, “Stereochemistry of hydrate copper(II) ions on the interlamellar surface of layer silicates. An electron spin resonance study,” Journal Physic Chemistry B, vol. 101, pp. 7786-7793, 1973.
[31] L. Guo, K. Ibrahim, F.Q. Liu, X.C. Ai, Q.S. Li, H.S. Zhu and Y.H. Zou. “Transient optical properties of novel PbS nanoparticles coated with 2,6-O-diallyl--CD,” Journal of Luminescence, vol. 82, pp. 111-114, 1999.
[32] P. Yang, C.F. Song, M.K. Lü, X. Yin, G.J. Zhou, D. Xu and D.R. Yuan, “The luminescence of PbS nanoparticles embedded in sol-gel silica glass,” Chemical Physics Letters, vol. 345, pp. 429-434, 2001.
[33] S.W. Buckner, R.L. Konold and P.A. Jelliss, “Luminescence quenching in PbS nanoparticles,” Chemical Physics Letters, vol. 394, pp. 400-404, 2004.
[34] M.S. Ghamsari, M.H.M. Ara, S. Radiman and X.H. Zhang, “Colloidal lead sulfide nanocrystals with strong green emission.” Journal of Luminescence, vol. 137, pp. 241-244, 2013.