A reduced scale spectrofluorometric method for determination of total petroleum hydrocarbon in seawater -
Article Sidebar
Main Article Content
Abstract
The Intergovernmental Oceanographic Commission (IOC) standard guide for determination of total petroleum hydrocarbon (TPH) in seawater was modified to conform to green analytical chemistry by reducing the volume of samples and extracted solvent. As a result, the pre-concentration factor was reduced from 800 to 20, which suitable to the normal high sensitivity spectrofluorometer currently available in the market. A calibration curve of chrysene without extraction was linear over a concentration range of 10-200 mg×L-1. The regression equation was y=1.567x+2.524 with the coefficient of determination (R2) 0.9992. Limit of detection (3sd/m, n=10) and limit of quantitation (10sd/m, n=10) were 0.065 and 0.22 mg×L-1, respectively. The proposed method was applied to determine TPH in seawater along Bangsean beach in Chonburi province, Thailand. A Collaborative Trials of this proposed method should be performed in order to accept it as a standard method.
Article Details
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
- Content and information in articles published in NKRAFA Journal of Science and Technology are comment and responsibility of authors of articles directly. Journal editorial do no need to agree or share any responsibility.
- NKRAFA Journal of Science and Technology Articles holds the copyright of the content, pictures, images etc. which published in it. If any person or agency require to reuse all or some part of articles, the permission must be obtained from the NKRAFA Journal of Science and Technology.
References
IOC/UNESCO (1984). Manual for monitoring Oil and Dissolved/dispersed Petroleum Hydrocarbons in Marine waters and on Beaches. . France. Available source: https://www.jodc.go.jp/info/ioc_doc/Manual/060618eb.pdf, March 31, 2020.,
Wattayakorn, G. (2012). Petroleum pollution in the Gulf of Thailand: A historical review. Coastal Marine Science, 35(1), 234-245.
ISO5725-3:1994. Accuracy (Trueness and Precision) of Measurement Methods and Results –Part 3: Intermediate Measures of the Precision of a Standard Measurement Method. Geneva, International Organization for Standardization.
ISO3534-2:2006. Statistics – Vocabulary and Symbols – Part 2: Applied Statistics. Geneva, International Organization for Standardization.
Thompson, M. & Lowthian, P.J. (2011). Notes on Statistics And Data Quality For Analytical Chemists. 1st ed, London, Imperial College Press.
AOAC (2016). Appendix F: Guidelines for Standard Method Performance Requirements, . Rockville, MD, USA. Available source: http://www.eoma.aoac.org/app_f.pdf, March 31, 2020., AOAC INTERNATIONAL.
Bícego, M.C., Zanardi-Lamardo, E. & Weber, R.R. (2003). Four-year survey of dissolved/dispersed petroleum hydrocarbons on surface waters of Admiralty Bay, King George Island, Antarctica. Revista Brasileira de Oceanografia, 51, 33-38.
Wattayakorn, G. & Rungsupa, S. (2012). Petroleum hydrocarbon residues in the marine environment of Koh Sichang-Sriracha, Thailand. Coastal Marine Science, 35(1), 122-128.
González, J.J., Viñas, L., Franco, M.A., Fumega, J., Soriano, J.A., Grueiro, G., Muniategui, S., López-Mahía, P., Prada, D., Bayona, J.M., Alzaga, R. & Albaigés, J. (2006). Spatial and temporal distribution of dissolved/dispersed aromatic hydrocarbons in seawater in the area affected by the Prestige oil spill. Marine Pollution Bulletin, 53(5), 250-259.
Shriadah, M.M.A. (2000). Levels and Distribution of Petroleum Hydrocarbons in the Coastal Waters and Sediments of the United Arab Emirates in the Arabian Gulf and the Gulf of Oman. Water, Air, and Soil Pollution, 119(1), 247-256.
Chouksey, M.K., Kadam, A.N. & Zingde, M.D. (2004). Petroleum hydrocarbon residues in the marine environment of Bassein–Mumbai. Marine Pollution Bulletin, 49(7), 637-647.
Nageswar, R.M., Ram, A., Rokade, M.A., Raja, P., Rakesh, P.S., Chemburkar, P. & Gajbhiye, S.N. (2016). Preliminary Estimate of Total Petroleum Hydrocarbons in Water and Some Commercially Important Fish Species in the Amba Estuary, West Coast of India. Bulletin Environmental Contamination Toxicology, 97(1), 56-62.
Pikkarainen, A.L. & Lemponen, P. (2005). Petroleum Hydrocarbon concentration in Baltic sea surface water. Boreal Environment Research, 10, 125-134.
Guardia, M. & Garrigues, S. (2012). Handbook of Green Analytical Chemistry. 1st ed, UK, John Wiley & Sons, Ltd.
Miller, J.M. & Miller, J.C. (2010). Statistics and Chemometrics for Analytical Chemistry. 6th ed, Gosport, UK., Ashford Colour Press Ltd.